Making the future. Nat. Synth. 1, 1 (2022).Kalmutzki, M. J., Hanikel, N. & Yaghi, O. M. Secondary building units as the turning point in the development of the reticular chemistry of MOFs. Sci. Adv. 4, eaat9180 (2018).Article
CAS
PubMed
PubMed Central
Google Scholar
Chen, Z. et al. Balancing volumetric and gravimetric uptake in highly porous materials for clean energy. Science 368, 297–303 (2020).Article
CAS
PubMed
Google Scholar
Freund, R. et al. The current status of MOF and COF applications. Angew. Chem. Int. Ed. 60, 23975–24001 (2021).Article
CAS
Google Scholar
Banerjee, S., Lollar, C. T., Xiao, Z., Fang, Y. & Zhou, H.-C. Biomedical integration of metal–organic frameworks. Trends Chem. 2, 467–479 (2020).Article
CAS
Google Scholar
Li, A. et al. The launch of a freely accessible MOF CIF collection from the CSD. Matter 4, 1105–1106 (2021).Article
CAS
Google Scholar
Yaghi, O. M. et al. Reticular synthesis and the design of new materials. Nature 423, 705–714 (2003).Article
CAS
PubMed
Google Scholar
Li, H., Eddaoudi, M., Groy, T. L. & Yaghi, O. M. Establishing microporosity in open metal–organic frameworks: gas sorption isotherms for Zn(BDC) (BDC = 1,4-benzenedicarboxylate). J. Am. Chem. Soc 120, 8571–8572 (1998).Article
CAS
Google Scholar
Li, H., Eddaoudi, M., O’Keeffe, M. & Yaghi, O. M. Design and synthesis of an exceptionally stable and highly porous metal–organic framework. Nature 402, 276–279 (1999).Article
CAS
Google Scholar
Jiang, H., Alezi, D. & Eddaoudi, M. A reticular chemistry guide for the design of periodic solids. Nat. Rev. Mater. 6, 466–487 (2021).Article
CAS
Google Scholar
Andreo, J. et al. Reticular nanoscience: bottom-up assembly nanotechnology. J. Am. Chem. Soc. 144, 7531–7550 (2022).Article
CAS
PubMed
Google Scholar
Guillerm, V. et al. A supermolecular building approach for the design and construction of metal–organic frameworks. Chem. Soc. Rev. 43, 6141–6172 (2014).Article
CAS
PubMed
Google Scholar
Wang, H. et al. Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers. Nat. Commun. 9, 1745 (2018).Article
PubMed
PubMed Central
Google Scholar
Bureekaew, S., Balwani, V., Amirjalayer, S. & Schmid, R. Isoreticular isomerism in 4,4-connected paddle-wheel metal–organic frameworks: structural prediction by the reverse topological approach. CrystEngComm 17, 344–352 (2014).Article
Google Scholar
Keupp, J. & Schmid, R. TopoFF: MOF structure prediction using specifically optimized blueprints. Faraday Discuss. 211, 79–101 (2018).Article
CAS
PubMed
Google Scholar
Baburin, I. A., Leoni, S. & Seifert, G. Enumeration of not-yet-synthesized zeolitic zinc imidazolate MOF networks: a topological and DFT approach. J. Phys. Chem. B 112, 9437–9443 (2008).Article
CAS
PubMed
Google Scholar
Lewis, D. W. et al. Zeolitic imidazole frameworks: structural and energetics trends compared with their zeolite analogues. CrystEngComm 11, 2272–2276 (2009).Article
CAS
Google Scholar
Yuan, S. et al. Retrosynthesis of multi-component metal–organic frameworks. Nat. Commun. 9, 808 (2018).Article
PubMed
PubMed Central
Google Scholar
Ortín-Rubio, B. et al. Net-clipping: an approach to deduce the topology of metal–organic frameworks built with zigzag ligands. J. Am. Chem. Soc. 142, 9135–9140 (2020).Article
PubMed
Google Scholar
Chen, Z., Jiang, H., Li, M., O’Keeffe, M. & Eddaoudi, M. Reticular chemistry 3.2: typical minimal edge-transitive derived and related nets for the design and synthesis of metal–organic frameworks. Chem. Rev. 120, 8039–8065 (2020).Article
CAS
PubMed
Google Scholar
Bai, Y. et al. Zr-based metal–organic frameworks: design, synthesis, structure, and applications. Chem. Soc. Rev. 45, 2327–2367 (2016).Article
CAS
PubMed
Google Scholar
Cavka, J. H. et al. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J. Am. Chem. Soc. 130, 13850–13851 (2008).Article
PubMed
Google Scholar
Trickett, C. A. et al. Identification of the strong brønsted acid site in a metal–organic framework solid acid catalyst. Nat. Chem. 11, 170–176 (2019).Article
CAS
PubMed
Google Scholar
Delgado-Friedrichs, O., O’Keeffe, M. & Yaghi, O. M. Taxonomy of periodic nets and the design of materials. Phys. Chem. Chem. Phys. 9, 1035–1043 (2007).Article
CAS
PubMed
Google Scholar
Li, M., Li, D., O’Keeffe, M. & Yaghi, O. M. Topological analysis of metal–organic frameworks with polytopic linkers and/or multiple building units and the minimal transitivity principle. Chem. Rev. 114, 1343–1370 (2014).Article
CAS
PubMed
Google Scholar
O’Keeffe, M., Peskov, M. A., Ramsden, S. J. & Yaghi, O. M. The Reticular Chemistry Structure Resource (RCSR) database of, and symbols for, crystal nets. Acc. Chem. Res. 41, 1782–1789 (2008).Article
PubMed
Google Scholar
Feng, D. et al. A highly stable porphyrinic zirconium metal–organic framework with shp-a topology. J. Am. Chem. Soc. 136, 17714–17717 (2014).Article
CAS
PubMed
Google Scholar
Cliffe, M. J. et al. Correlated defect nanoregions in a metal–organic framework. Nat. Commun. 5, 4176 (2014).Article
CAS
PubMed
Google Scholar
Richardson, J. S. Early ribbon drawings of proteins. Nat. Struct. Biol. 7, 624–625 (2000).Article
CAS
PubMed
Google Scholar
Richardson, J. S. The anatomy and taxonomy of protein structure. Adv. Protein Chem. 34, 167–339 (1981).Guillerm, V., Grancha, T., Imaz, I., Juanhuix, J. & Maspoch, D. Zigzag ligands for transversal design in reticular chemistry: unveiling new structural opportunities for metal–organic frameworks. J. Am. Chem. Soc. 140, 10153–10157 (2018).Article
CAS
PubMed
Google Scholar
Kim, H. et al. Symmetry-guided syntheses of mixed-linker Zr metal–organic frameworks with precise linker locations. Chem. Sci. 10, 5801–5806 (2019).Article
CAS
PubMed
PubMed Central
Google Scholar
Bon, V., Senkovskyy, V., Senkovska, I. & Kaskel, S. Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology. Chem. Commun. 48, 8407–8409 (2012).Article
CAS
Google Scholar
Furukawa, H. et al. Water adsorption in porous metal–organic frameworks and related materials. J. Am. Chem. Soc. 136, 4369–4381 (2014).Article
CAS
PubMed
Google Scholar
Mondloch, J. E. et al. Vapor-phase metalation by atomic layer deposition in a metal–organic framework. J. Am. Chem. Soc. 135, 10294–10297 (2013).Article
CAS
PubMed
Google Scholar
Kassie, A. A. et al. Postsynthetic metal exchange in a metal–organic framework assembled from Co(III) diphosphine pincer complexes. Inorg. Chem. 58, 3227–3236 (2019).Article
CAS
PubMed
Google Scholar
Feng, D. et al. Construction of ultrastable porphyrin Zr metal–organic frameworks through linker elimination. J. Am. Chem. Soc. 135, 17105–17110 (2013).Article
CAS
PubMed
Google Scholar
Materials Studio v 7.0 (Accelrys, 2013).Nguyen, H. T. T. et al. Combining linker design and linker-exchange strategies for the synthesis of a stable large-pore Zr-based metal–organic framework. ACS Appl. Mater. Interfaces 10, 35462–35468 (2018).Article
CAS
PubMed
Google Scholar
Cheng, S. et al. Charge separation in metal–organic framework enables heterogeneous thiol catalysis. Angew. Chem. Int. Ed. https://doi.org/10.1002/anie.202300993 (2023).Hu, X. et al. Nanoscale metal–organic frameworks and metal–organic layers with two-photon-excited fluorescence. Inorg. Chem. 59, 4181–4185 (2020).Article
CAS
PubMed
Google Scholar
Chen, X. et al. Direct observation of modulated radical spin states in metal–organic frameworks by controlled flexibility. J. Am. Chem. Soc. 144, 2685–2693 (2022).Article
CAS
PubMed
Google Scholar
Roy, S. et al. Electrocatalytic hydrogen evolution from a cobaloxime-based metal–organic framework thin film. J. Am. Chem. Soc. 141, 15942–15950 (2019).Article
CAS
PubMed
PubMed Central
Google Scholar
Wang, S. et al. A zirconium metal–organic framework with SOC topological net for catalytic peptide bond hydrolysis. Nat. Commun. 13, 1284 (2022).Article
CAS
PubMed
PubMed Central
Google Scholar
Lee, S. & Yaghi, O. M. ‘Eye’ of the molecule—a viewpoint. Faraday Discuss. 231, 145–149 (2021).Article
CAS
PubMed
Google Scholar
Wang, T. C. et al. Ultrahigh surface area zirconium MOFs and insights into the applicability of the BET theory. J. Am. Chem. Soc. 137, 3585–3591 (2015).Article
CAS
PubMed
Google Scholar
Lin, Q. et al. New heterometallic zirconium metalloporphyrin frameworks and their heteroatom-activated high-surface-area carbon derivatives. J. Am. Chem. Soc. 137, 2235–2238 (2015).Article
CAS
PubMed
Google Scholar
Gong, X. et al. Metal–organic frameworks for the exploitation of distance between active sites in efficient photocatalysis. Angew. Chem. Int. Ed. 59, 5326–5331 (2020).Article
CAS
Google Scholar
Choi, E.-Y. et al. Pillared porphyrin homologous series: intergrowth in metal−organic frameworks. Inorg. Chem. 48, 426–428 (2009).Article
CAS
PubMed
Google Scholar
Barsukova, M. et al. Face-directed assembly of tailored isoreticular MOFs using centring structure-directing agents. Nat. Synth. 3, 33–46 (2024).Article
Google Scholar
Ma, J., Kalenak, A. P., Wong-Foy, A. G. & Matzger, A. J. Rapid guest exchange and ultra-low surface tension solvents optimize metal–organic framework activation. Angew. Chem. Int. Ed. 56, 14618–14621 (2017).Article
CAS
Google Scholar
Yu, F., Hu, B.-Q. & Li, B. A zirconium–organic framework incorporating with amino and sulfoxide groups. Inorg. Chem. Commun. 107, 107484 (2019).Article
CAS
Google Scholar
Deria, P. et al. Framework-topology-dependent catalytic activity of zirconium-based (porphinato)zinc(II) MOFs. J. Am. Chem. Soc. 138, 14449–14457 (2016).Article
CAS
PubMed
Google Scholar
Feng, D. et al. Zirconium–metalloporphyrin PCN-222: mesoporous metal–organic frameworks with ultrahigh stability as biomimetic catalysts. Angew. Chem. Int. Ed. 51, 10307–10310 (2012).Article
CAS
Google Scholar
Sheng, W., Wang, X., Wang, Y., Chen, S. & Lang, X. Integrating TEMPO into a metal–organic framework for cooperative photocatalysis: selective aerobic oxidation of sulfides. ACS Catal. 12, 11078–11088 (2022).Article
CAS
Google Scholar
Valverde, A. et al. Designing metal-chelator-like traps by encoding amino acids in zirconium-based metal–organic frameworks. Chem. Mater. 34, 9666–9684 (2022).Article
CAS
Google Scholar
Li, X.-M., Wang, Y., Mu, Y., Gao, J. & Zeng, L. Oriented construction of efficient intrinsic proton transport pathways in MOF-808. J. Mater. Chem. A 10, 18592–18597 (2022).Article
CAS
Google Scholar
Wilmer, C. E. et al. Large-scale screening of hypothetical metal–organic frameworks. Nat. Chem. 4, 83–89 (2012).Article
CAS
Google Scholar
Colón, Y. J., Gómez-Gualdrón, D. A. & Snurr, R. Q. Topologically guided, automated construction of metal–organic frameworks and their evaluation for energy-related applications. Cryst. Growth Des. 17, 5801–5810 (2017).Article
Google Scholar
Moghadam, P. Z., Chung, Y. G. & Snurr, R. Q. Progress toward the computational discovery of new metal–organic framework adsorbents for energy applications. Nat. Energy 9, 121–133 (2024).Article
CAS
Google Scholar