Francl, M. Heart of glass. Nat. Chem. 14, 717–718 (2022).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Zimmerman, J. B., Anastas, P. T., Erythropel, H. C. & Leitner, W. Designing for a green chemistry future. Science 367, 397–400 (2020).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Xing, R., Yuan, C., Fan, W., Ren, X. & Yan, X. Biomolecular glass with amino acid and peptide nanoarchitectonics. Sci. Adv. 9, eadd8105 (2023).ArticleÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Cao, S., Fan, W., Chang, R., Yuan, C. & Yan, X. Metal ion-coordinated biomolecular noncovalent glass with ceramic-like mechanics. CCS Chem. https://doi.org/10.31635/ccschem.024.202303832 (2024).Wang, C., Yokota, T. & Someya, T. Natural biopolymer-based biocompatible conductors for stretchable bioelectronics. Chem. Rev. 121, 2109–2146 (2021).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
La, T.-G. & Le, L. H. Flexible and wearable ultrasound device for medical applications: a review on materials, structural designs, and current challenges. Adv. Mater. Technol. 7, 2100798 (2022).ArticleÂ
Google ScholarÂ
Song, Q. et al. Molecular self-assembly and supramolecular chemistry of cyclic peptides. Chem. Rev. 121, 13936–13995 (2021).ArticleÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Sheehan, F. et al. Peptide-based supramolecular systems chemistry. Chem. Rev. 121, 13869–13914 (2021).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Hu, K. et al. Tuning peptide self-assembly by an in-tether chiral center. Sci. Adv. 4, eaar5907 (2018).ArticleÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Borthwick, A. D. 2,5-Diketopiperazines: synthesis, reactions, medicinal chemistry, and bioactive natural products. Chem. Rev. 112, 3641–3716 (2012).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Bellezza, I., Peirce, M. J. & Minelli, A. Cyclic dipeptides: from bugs to brain. Trends Mol. Med. 20, 551–558 (2014).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Fan, Z. et al. Near infrared fluorescent peptide nanoparticles for enhancing esophageal cancer therapeutic efficacy. Nat. Commun. 9, 2605 (2018).ArticleÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Tao, K. et al. Quantum confined peptide assemblies with tunable visible to near-infrared spectral range. Nat. Commun. 9, 3217 (2018).ArticleÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Merz, M. L. et al. De novo development of small cyclic peptides that are orally bioavailable. Nat. Chem. Biol. 20, 624–633 (2024).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Muttenthaler, M., King, G. F., Adams, D. J. & Alewood, P. F. Trends in peptide drug discovery. Nat. Rev. Drug Discov. 20, 309–325 (2021).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Chen, Y. et al. Self-assembly of cyclic dipeptides: platforms for functional materials. Protein Pept. Lett. 27, 688–697 (2020).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Yan, X., Su, Y., Li, J., Früh, J. & Möhwald, H. Uniaxially oriented peptide crystals for active optical waveguiding. Angew. Chem. Int. Ed. 50, 11186–11191 (2011).ArticleÂ
CASÂ
Google ScholarÂ
Yang, M. et al. Cyclic dipeptide nanoribbons formed by dye-mediated hydrophobic self-assembly for cancer chemotherapy. J. Colloid Interface Sci. 557, 458–464 (2019).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Manchineella, S. & Govindaraju, T. Molecular self-assembly of cyclic dipeptide derivatives and their applications. ChemPlusChem. 82, 88–106 (2016).ArticleÂ
PubMedÂ
Google ScholarÂ
Chang, R., Yuan, C., Zhou, P., Xing, R. & Yan, X. Peptide self-assembly: from ordered to disordered. Acc. Chem. Res. 57, 289–301 (2024).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Yuan, C. et al. Hierarchically oriented organization in supramolecular peptide crystals. Nat. Rev. Chem. 3, 567–588 (2019).ArticleÂ
CASÂ
Google ScholarÂ
Greer, A. L. Confusion by design. Nature 366, 303–304 (1993).ArticleÂ
Google ScholarÂ
Perim, E. et al. Spectral descriptors for bulk metallic glasses based on the thermodynamics of competing crystalline phases. Nat. Commun. 7, 12315 (2016).ArticleÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Ke, Y. et al. Smart windows: electro-, thermo-, mechano-, photochromics, and beyond. Adv. Energy Mater. 9, 1902066 (2019).ArticleÂ
CASÂ
Google ScholarÂ
Kasimuthumaniyan, S., Reddy, A. A., Krishnan, N. M. A. & Gosvami, N. N. Understanding the role of post-indentation recovery on the hardness of glasses: case of silica, borate, and borosilicate glasses. J. Non-Cryst. Solids 534, 119955 (2020).ArticleÂ
CASÂ
Google ScholarÂ
Knowles, T. P. J. & Buehler, M. J. Nanomechanics of functional and pathological amyloid materials. Nat. Nanotechnol. 6, 469–479 (2011).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Fang, W. et al. Organic–inorganic covalent–ionic molecules for elastic ceramic plastic. Nature 619, 293–299 (2023).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Hong, Y. P. et al. Crystal structure and spectroscopic properties of cyclic dipeptide: a racemic mixture of cyclo(d-prolyl-l-tyrosyl) and cyclo(l-prolyl-d-tyrosyl). Bull. Korean Chem. Soc. 35, 2299–2303 (2014).ArticleÂ
CASÂ
Google ScholarÂ
Rozenberg, M., Shoham, G., Reva, I. & Fausto, R. A correlation between the proton stretching vibration red shift and the hydrogen bond length in polycrystalline amino acids and peptides. Phys. Chem. Chem. Phys. 7, 2376–2383 (2005).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Bertoldo Menezes, D. et al. Raman spectroscopic insights into the glass transition of poly(methyl methacrylate). Phys. Chem. Chem. Phys. 23, 1649–1665 (2021).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Swallen, S. F. et al. Organic glasses with exceptional thermodynamic and kinetic stability. Science 315, 353–356 (2007).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Ito, K., Moynihan, C. T. & Angell, C. A. Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water. Nature 398, 492–495 (1999).ArticleÂ
CASÂ
Google ScholarÂ
Smedskjaer, M. M. et al. Topological principles of borosilicate glass chemistry. J. Phys. Chem. B 115, 12930–12946 (2011).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Wang, L.-M., Angell, C. A. & Richert, R. Fragility and thermodynamics in nonpolymeric glass-forming liquids. J. Chem. Phys. 125, 074505 (2006).ArticleÂ
PubMedÂ
Google ScholarÂ
Böhmer, R., Ngai, K. L., Angell, C. A. & Plazek, D. J. Nonexponential relaxations in strong and fragile glass formers. J. Chem. Phys. 99, 4201–4209 (1993).ArticleÂ
Google ScholarÂ
Greaves, G. N., Greer, A. L., Lakes, R. S. & Rouxel, T. Poisson’s ratio and modern materials. Nat. Mater. 10, 823–837 (2011).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Huang, D. & McKenna, G. B. New insights into the fragility dilemma in liquids. J. Chem. Phys. 114, 5621–5630 (2001).ArticleÂ
CASÂ
Google ScholarÂ
Rodrigues, A. C., Viciosa, M. T., Danède, F., Affouard, F. & Correia, N. T. Molecular mobility of amorphous S-flurbiprofen: a dielectric relaxation spectroscopy approach. Mol. Pharm. 11, 112–130 (2014).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Shi, Y. et al. Revealing the relationship between liquid fragility and medium-range order in silicate glasses. Nat. Commun. 14, 13 (2023).ArticleÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Novikov, V. N. Upper bound of fragility from spatial fluctuations of shear modulus and boson peak in glasses. Phys. Rev. E 106, 024611 (2022).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Kaushal, A. M. & Bansal, A. K. Thermodynamic behavior of glassy state of structurally related compounds. Eur. J. Pharm. Biopharm. 69, 1067–1076 (2008).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Miracle, D. B. & Senkov, O. N. A critical review of high entropy alloys and related concepts. Acta Mater. 122, 448–511 (2017).ArticleÂ
CASÂ
Google ScholarÂ
Yang, M. et al. High thermal stability and sluggish crystallization kinetics of high-entropy bulk metallic glasses. J. Appl. Phys. 119, 245112 (2016).ArticleÂ
Google ScholarÂ
Rà fols-Ribé, J. et al. High-performance organic light-emitting diodes comprising ultrastable glass layers. Sci. Adv. 4, eaar8332 (2018).ArticleÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Willcott, M. R. MestRe Nova. J. Am. Chem. Soc. 131, 13180 (2009).ArticleÂ
CASÂ
Google ScholarÂ
Oliver, W. C. & Pharr, G. M. An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mater. Res. 7, 1564–1583 (1992).ArticleÂ
CASÂ
Google ScholarÂ
Jiang, B. et al. High-entropy-stabilized chalcogenides with high thermoelectric performance. Science 371, 830–834 (2021).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Van Der Spoel, D. et al. GROMACS: fast, flexible, and free. J. Comput. Chem. 26, 1701–1718 (2005).ArticleÂ
PubMedÂ
Google ScholarÂ
Ulmschneider, J. P. & Jorgensen, W. L. Polypeptide folding using Monte Carlo sampling, concerted rotation, and continuum solvation. J. Am. Chem. Soc. 126, 1849–1857 (2004).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Abascal, J. L. F. & Vega, C. A general purpose model for the condensed phases of water: TIP4P/2005. J. Chem. Phys. 123, 234505 (2005).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Brooks, B. R. et al. CHARMM: a program for macromolecular energy, minimization, and dynamics calculations. J. Comput. Chem. 4, 187–217 (1983).ArticleÂ
CASÂ
Google ScholarÂ
Hess, B., Bekker, H., Berendsen, H. J. C. & Fraaije, J. G. E. M. LINCS: a linear constraint solver for molecular simulations. J. Comput. Chem. 18, 1463–1472 (1997).ArticleÂ
CASÂ
Google ScholarÂ
Berendsen, H. J. C., Postma, J. P. M., van Gunsteren, W. F., DiNola, A. & Haak, J. R. Molecular dynamics with coupling to an external bath. J. Chem. Phys. 81, 3684–3690 (1984).ArticleÂ
CASÂ
Google ScholarÂ
Bussi, G., Donadio, D. & Parrinello, M. Canonical sampling through velocity rescaling. J. Chem. Phys. 126, 014101 (2007).ArticleÂ
PubMedÂ
Google ScholarÂ
Tao, K. et al. Bioinspired supramolecular packing enables high thermo-sustainability. Angew. Chem. Int. Ed. 59, 19037–19041 (2020).ArticleÂ
CASÂ
Google ScholarÂ
Burley, S. K. & Petsko, G. A. Aromatic-aromatic interaction: a mechanism of protein structure stabilization. Science 229, 23–28 (1985).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Ogliaro, F. et al. Gaussian 09, revision A. 02. (Gaussian, 2009).Boys, S. F. & Bernardi, F. The calculation of small molecular interactions by the differences of separate total energies. Some procedures with reduced errors. Mol. Phys. 19, 553–566 (1970).ArticleÂ
CASÂ
Google ScholarÂ
Lu, T. & Chen, F. Multiwfn: a multifunctional wavefunction analyzer. J. Comput. Chem. 33, 580–592 (2012).ArticleÂ
PubMedÂ
Google ScholarÂ
Yuan, C. et al. Cyclic Peptide High-Entropy Noncovalent Glass. Figshare https://doi.org/10.6084/m9.figshare.26181884 (2024).