POSS – Hybrid Plastics. Regist. trademark.Cordes, D. B., Lickiss, P. D. & Rataboul, F. Recent developments in the chemistry of cubic polyhedral. Chem. Rev. 110, 2081–2173 (2010).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Laird, M. et al. Large polyhedral oligomeric silsesquioxane cages: The isolation of functionalized POSS with an unprecedented Si18O27 core. Angew. Chem. Int. Ed. 60, 3022–3027 (2021).ArticleÂ
CASÂ
Google ScholarÂ
Dudziec, B. & Marciniec, B. Double-decker silsesquioxanes: Current chemistry and applications. Curr. Org. Chem. 21, 2794–2813 (2017).CASÂ
Google ScholarÂ
Wang, M., Chi, H., Joshy, K. S. & Wang, F. Progress in the synthesis of bifunctionalized polyhedral oligomeric silsesquioxane. Polymers (Basel) 11, 2098–2118 (2019).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Li, L., Wang, H. & Zheng, S. Well-defined difunctional POSS macromers and related organic–inorganic polymers: Precision synthesis, structure and properties. J. Polym. Sci. https://doi.org/10.1002/pol.20230428 (2023).ArticleÂ
Google ScholarÂ
Ye, Q., Zhou, H. & Xu, J. Cubic polyhedral oligomeric silsesquioxane based functional materials: Synthesis, assembly, and applications. Chem. Asian J. 11, 1322–1337 (2016).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Zhou, H., Ye, Q. & Xu, J. Polyhedral oligomeric silsesquioxane-based hybrid materials and their applications. Mater. Chem. Front. 1, 212–230 (2017).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Gon, M., Tanaka, K. & Chujo, Y. Recent progress on designable hybrids with stimuli-responsive optical properties originating from molecular assembly concerning polyhedral oligomeric silsesquioxane. Chem. Asian J. 17, e202200144 (2022).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Calabrese, C., Aprile, C., Gruttadauria, M. & Giacalone, F. POSS nanostructures in catalysis. Catal. Sci. Technol. 10, 7415–7447 (2020).ArticleÂ
CASÂ
Google ScholarÂ
Wang, L. et al. Multi-stimuli-responsive nanoparticles formed of POSS-PEG for the delivery of boronic acid-containing therapeutics. Biomacromolecules 24, 5071–5082 (2023).ArticleÂ
PubMedÂ
Google ScholarÂ
Jafari, M. et al. Dendritic hybrid materials comprising polyhedral oligomeric silsesquioxane (POSS) and hyperbranched polyglycerol for effective antifungal drug delivery and therapy in systemic candidiasis. Nanoscale 15, 16163–16177 (2023).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Poggi, E. & Gohy, J. F. Janus particles: From synthesis to application. Colloid Polym. Sci. 295, 2083–2108 (2017).ArticleÂ
CASÂ
Google ScholarÂ
Walther, A. & Mu, A. H. E. Janus particles: Synthesis, self-assembly, physical properties, and applications. Chem. Rev. https://doi.org/10.1021/cr300089t (2013).ArticleÂ
PubMedÂ
Google ScholarÂ
Synytska, A., Khanum, R., Ionov, L., Cherif, C. & Bellmann, C. Water-repellent textile via decorating fibers with amphiphilic Janus Particles. ACS Appl. Mater. Interfaces 3, 1216–1220 (2011).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Walther, A. & Müller, A. H. E. Janus particles. Soft Matter 4, 663–668 (2008).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Xu, L., Pradhan, S. & Chen, S. Adhesion force studies of Janus nanoparticles. Langmuir https://doi.org/10.1021/la700774g (2007).ArticleÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Wu, L. Y., Ross, B. M., Hong, S. & Lee, L. P. Bioinspired nanocorals with decoupled cellular targeting and sensing functionality **. Small https://doi.org/10.1002/smll.200901604 (2010).ArticleÂ
PubMedÂ
Google ScholarÂ
Valadares, L. F. et al. Catalytic nanomotors: Self-propelled sphere dimers. Small https://doi.org/10.1002/smll.200901976 (2010).ArticleÂ
PubMedÂ
Google ScholarÂ
Chinnam, P. R. & Wunder, S. L. Polyoctahedral silsesquioxane-nanoparticle electrolytes for lithium batteries: POSS-lithium salts and POSS-PEGs. Chem. Mater. 23, 5111–5121 (2011).ArticleÂ
CASÂ
Google ScholarÂ
Han, D., Zhang, Q., Chen, F. & Fu, Q. RSC advances using POSS—C 60 giant molecules as a novel compatibilizer for PS / PMMA polymer blends †. RSC Adv. 6, 18924–18928 (2016).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Han, D. et al. AC SC. Polymer (Guildf). 136, 84–91 (2018).ArticleÂ
CASÂ
Google ScholarÂ
Anker, J. N., Behrend, C. J., Huang, H. & Kopelman, R. Magnetically-modulated optical nanoprobes (MagMOONs) and systems. J. Magn. Magn. Mater. 293, 655–662 (2005).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Xu, H., Aylott, J. W., Kopelman, R., Miller, T. J. & Philbert, M. A. A real-time ratiometric method for the determination of molecular oxygen inside living cells using sol-gel-based spherical optical nanosensors with applications to rat C6 glioma. Anal. Chem. 73, 4124–4133 (2001).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Behrend, C. J. et al. Metal-capped Brownian and magnetically modulated optical nanoprobes (MOONs): Micromechanics in chemical and biological microenvironments †. J. Phys. Chem. B 108, 10408–10414 (2004).ArticleÂ
CASÂ
Google ScholarÂ
Tanaka, T., Hasegawa, Y., Kawamori, T., Kunthom, R. & Takeda, N. Synthesis of double-decker silsesquioxanes from substituted difluorosilane. Organometallics https://doi.org/10.1021/acs.organomet.8b00896 (2018).ArticleÂ
Google ScholarÂ
Asuncion, M. Z., Ronchi, M., Abu-Seir, H. & Laine, R. M. Synthesis, functionalization and properties of incompletely condensed ‘half cube’ silsesquioxanes as a potential route to nanoscale Janus particles. Comptes Rendus Chim. 13, 270–281 (2010).ArticleÂ
CASÂ
Google ScholarÂ
Oguri, N., Egawa, Y., Takeda, N. & Unno, M. Janus-cube octasilsesquioxane: Facile synthesis and structure elucidation. Angew. Chem. Int. Ed. 55, 9336–9339 (2016).ArticleÂ
CASÂ
Google ScholarÂ
Shiba, H., Yoshikawa, M., Wada, H., Shimojima, A. & Kuroda, K. Synthesis of polycyclic and cage siloxanes by hydrolysis and intramolecular condensation of alkoxysilylated cyclosiloxanes. Chem. Eur. J. https://doi.org/10.1002/chem.201805942 (2019).ArticleÂ
PubMedÂ
Google ScholarÂ
Blázquez-Moraleja, A., Pérez-Ojeda, M. E., Ramón Suárez, J., Jimeno, M. L. & Chiara, J. L. Chemical communications. Chem. Commun. 52, 5792–5795 (2016).ArticleÂ
Google ScholarÂ
Chen, X. et al. Science of the total environment single step synthesis of Janus nano-composite membranes by atmospheric aerosol plasma polymerization for solvents separation. Sci. Total Environ. 645, 22–33 (2018).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Meng, Y., Li, W., Kunthom, R., Liu, H. Rational Design and Application of Superhydrophobic Fluorine-Free Coating Basedon Double-Decker Silsesquioxane for Oil-Water Separation. Polymer 304, 127143 (2024)ArticleÂ
CASÂ
Google ScholarÂ
Li, W.; Liu, H. Rational Design and Facile Preparation of Hybrid Superhydrophobic Epoxy Coatings Modified byFluorinated Silsesquioxane-Based Giant Molecules via Photo-Initiated Thiol-Ene Click Reaction with Potential Applications.Chem. Eng. J. 480, 147943 (2024)ArticleÂ
CASÂ
Google ScholarÂ
Laine, R. M. et al. Perfect and nearly perfect silsesquioxane (SQs) nanoconstruction sites and Janus SQs. J. Sol Gel Sci. Technol. 46, 335–347 (2008).ArticleÂ
CASÂ
Google ScholarÂ
Liu, H. et al. Unraveling the self-assembly of hetero-cluster Janus dumbbells into hybrid cubosomes with internal double diamond structure. J. Am. Chem. Soc. https://doi.org/10.1021/jacs.8b08016 (2018).ArticleÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Ma, C. et al. A filled-honeycomb-structured crystal formed by self-assembly of a Janus polyoxometalate – silsesquioxane (POM – POSS) co-cluster Angewandte. Angew. Chem. Int. Ed. Engl. 54, 15699–15704 (2015).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Wang, F., Phonthammachai, N., Mya, K. Y., Tjiu, W. W. & He, C. PEG-POSS assisted facile preparation of amphiphilic gold nanoparticles and interface formation of Janus nanoparticles. Chem. Commun. 47, 767–769 (2011).ArticleÂ
CASÂ
Google ScholarÂ
Liu, H. et al. Manipulation of self-assembled nanostructure dimensions in molecular Janus particles. ACS Nano https://doi.org/10.1021/acsnano.6b01336 (2016).ArticleÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Liu, H. et al. Two-dimensional nanocrystals of molecular Janus particles. J. Am. Chem. Soc. 136, 10691–10699 (2014).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Marciniec, B., Pietraszuk, C., Pawluć, P. & Maciejewski, H. Inorganometallics (transition metal-metalloid complexes) and catalysis. Chem. Rev. 122, 3996–4090 (2022).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Troegel, D. & Stohrer, J. Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view. Coord. Chem. Rev. 255, 1440–1459 (2011).ArticleÂ
CASÂ
Google ScholarÂ
Walczak, M. et al. Hydrosilylation of alkenes and alkynes with silsesquioxane (HSiMe2O)(i-Bu)7Si8O12 catalyzed by Pt supported on a styrene-divinylbenzene copolymer. J. Catal. 367, 1–6 (2018).ArticleÂ
CASÂ
Google ScholarÂ
Walczak, M. et al. Unusual cis- and trans- architecture of dihydrofunctional double-decker shaped silsesquioxane – design and construction of its ethyl bridged Ï€-conjugated arene derivatives. New J. Chem. 41, 3290–3296 (2017).ArticleÂ
CASÂ
Google ScholarÂ
MituÅ‚a, K., Dutkiewicz, M., Dudziec, B., Marciniec, B. & Czaja, K. A library of monoalkenylsilsesquioxanes as potential comonomers for synthesis of hybrid materials. J. Therm. Anal. Calorim. 132, 1545–1555 (2018).ArticleÂ
Google ScholarÂ
Duszczak, J. et al. Distinct insight into the use of difunctional double-decker silsesquioxanes as building blocks for alternating A-B type macromolecular frameworks. Inorg. Chem. Front. 10, 888–899 (2022).ArticleÂ
Google ScholarÂ
Mrzygłód, A., Rzonsowska, M. & Dudziec, B. Exploring polyol-functionalized dendrimers with silsesquioxane cores. Inorg. Chem. 62, 21343–21352 (2023).ArticleÂ
PubMedÂ
Google ScholarÂ
Best, R. B. et al. Optimization of the additive CHARMM all-atom protein force field targeting improved sampling of the backbone φ, ψ and side-chain χ1 and χ2 dihedral angles. J. Chem. Theory Comput. 8, 3257–3273 (2012).ArticleÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Saam, J., Ivanov, I., Walther, M., Holzhütter, H. G. & Kuhn, H. Molecular dioxygen enters the active site of 12/15-lipoxygenase via dynamic oxygen access channels. Proc. Natl. Acad. Sci. U. S. A. 104, 13319–13324 (2007).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Humphrey, W., Dalke, A. & Schulten, K. VMD: Visual molecular dynamics. Proc. Natl. Acad. Sci. U. S. A. 104, 13319–13324 (2007).
Google ScholarÂ
Becke, A. D. Density-functional exchange-energy approximation with correct asymptotic behavior. Phys. Rev. Lett. 38, 3098–3100 (1988).ADSÂ
CASÂ
Google ScholarÂ
Ditchfield, R., Hehre, W. J. & Pople, J. A. Self-consistent molecular-orbital methods. IX. An extended Gaussian-type basis for molecular-orbital studies of organic molecules. J. Chem. Phys. 54, 720–723 (1971).ArticleÂ
ADSÂ
Google ScholarÂ
Reed, A. E., Weinstock, R. B. & Weinhold, F. Natural population analysis. J. Chem. Phys. 83, 735–746 (1985).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Frish, M. J. et al. Gaussian 09, Revision A.1 (Gaussian Inc., 2009).
Google ScholarÂ
Solvate Plugin, Version 1.5. https://www.ks.uiuc.edu/Research/vmd/plugins/solva at (2021).The Energy Function – CHARMM tutorial. https://www.charmmtutorial.org/index.php/The_Energ at (2021).Kirkpatrick, S., Gelatt, C. D. & Vecchi, M. P. Optimization by simulated annealing. Science 220, 671–680 (1983).ArticleÂ
ADSÂ
MathSciNetÂ
CASÂ
PubMedÂ
Google ScholarÂ
Franz, A., Hoffmann, K. H. & Salamon, P. Best possible strategy for finding ground states. Phys. Rev. Lett. 86, 5219–5222 (2001).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Allen, M. P. & Tildesley, D. J. Computer Simulation of Liquids (Clarendon Press, 1989).
Google ScholarÂ
Phillips, J. C. et al. Scalable molecular dynamics with NAMD. J. Comput. Chem. 26, 1781–1802 (2005).ArticleÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Coutsias, E. A., Seok, C. & Dill, K. A. Using quaternions to calculate RMSD. J. Comput. Chem. 25, 1849–1857 (2004).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Heyer, L. J., Kruglyak, S. & Yooseph, S. Exploring expression data identification and analysis of coexpressed genes. Genome Res. 9, 1106–1115 (1999).ArticleÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Clustering plugin for VMD. http://physiology.med.cornell.edu/faculty/hweinste at (2019).Becke, A. D. Density-functional thermochemistry. III. The role of exact exchange. J. Chem. Phys. 98, 5648–5652 (1993).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Petersson, G. A., Mohammad, A. & Laham, A. A complete basis set model chemistry. II. The total energies of open-shell atoms and hydrides of the first-row atoms. J. Chem. Phys. 9, 6081–6090 (1991).ArticleÂ
ADSÂ
Google ScholarÂ
Asaduzzaman, A., Runge, K., Muralidharan, K., Deymier, P. A. & Zhang, L. Energetics of substituted polyhedral oligomeric silsesquioxanes: A DFT study. MRS Commun. 5, 519–524 (2015).ArticleÂ
CASÂ
Google ScholarÂ
Asaduzzaman, A., Runge, K., Deymier, P. A. & Muralidharan, K. The role of aluminum substitution on the stability of substituted polyhedral oligomeric silsesquioxanes. Zeitschrift Fur Phys. Chem. 230, 1005–1014 (2016).ArticleÂ
CASÂ
Google ScholarÂ
Muya, J. T., Ceulemans, A., Gopakumar, G. & Parish, C. A. Jahn-teller distortion in polyoligomeric silsesquioxane (POSS) cations. J. Phys. Chem. A 119, 4237–4243 (2015).ArticleÂ
Google ScholarÂ
Tomasi, J., Mennucci, B. & Cammi, R. Quantum mechanical continuum solvation models. Chem. Rev. 105, 2999–3093 (2005).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Sokolnicki, T., Franczyk, A., Janowski, B. & Walkowiak, J. Synthesis of bio-based silane coupling agents by the modification of eugenol. Adv. Synth. Catal. 363, 5493–5500 (2021).ArticleÂ
CASÂ
Google ScholarÂ
Stefanowska, K. et al. Selective hydrosilylation of alkynes with octaspherosilicate (HSiMe2O)8Si8O12. Chem. Asian J. 13, 2101–2108 (2018).ArticleÂ
CASÂ
Google ScholarÂ
Spoljaric, S. & Shanks, R. A. Poly (styrene- b -butadiene- b -styrene)—dye-coupled polyhedral oligomeric silsesquioxanes. Adv. Mater. Res. 125, 169–172 (2010).ArticleÂ
Google ScholarÂ
Yuasa, S., Sato, Y., Imoto, H. & Naka, K. Thermal properties of open-cage silsesquioxanes: The effect of substituents at the corners and opening moieties. Bulletin Chem. Soc. Jpn. 92, 127–132 (2019).ArticleÂ
CASÂ
Google ScholarÂ