Sun, H. T. et al. Hierarchical 3D electrodes for electrochemical energy storage. Nat. Rev. Mater. 4, 45–60 (2019).Article
Google Scholar
Sun, Y. L., Liu, B., Liu, L. Y. & Yan, X. B. Ions transport in electrochemical energy storage devices at low temperatures. Adv. Funct. Mater. 32, 2109568 (2022).Article
CAS
Google Scholar
Xiao, K., Jiang, L. & Antonietti, M. Ion transport in nanofluidic devices for energy harvesting. Joule 3, 2364–2380 (2019).Article
CAS
Google Scholar
Chen, J. et al. Localized electrons enhanced ion transport for ultrafast electrochemical energy storage. Adv. Mater. 32, e1905578 (2020).Article
PubMed
Google Scholar
Yan, C. et al. Engineering 2D nanofluidic Li-ion transport channels for superior electrochemical energy storage. Adv. Mater. 29, 1703909 (2017).Article
Google Scholar
Lin, P. & Yan, F. Organic thin-film transistors for chemical and biological sensing. Adv. Mater. 24, 34–51 (2012).Article
PubMed
Google Scholar
Jentsch, T. J. VRACs and other ion channels and transporters in the regulation of cell volume and beyond. Nat. Rev. Mol. Cell Biol. 17, 293–307 (2016).Article
CAS
PubMed
Google Scholar
Ratner, M. A. & Shriver, D. F. Ion-transport in solvent-free polymers. Chem. Rev. 88, 109–124 (1988).Article
CAS
Google Scholar
Armand, M. & Tarascon, J. M. Building better batteries. Nature 451, 652–657 (2008).Article
CAS
PubMed
Google Scholar
Shen, C. T., Zhao, Q. J., Shan, N. S., Jing, B. B. & Evans, C. M. Conductivity–modulus–Tg relationships in solvent‐free, single lithium ion conducting network electrolytes. J. Polym. Sci. 58, 2376–2388 (2020).Article
CAS
Google Scholar
Bouchet, R. et al. Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries. Nat. Mater. 12, 452–457 (2013).Article
CAS
PubMed
Google Scholar
Sun, C. G. et al. Fast lithium ion transport in solid polymer electrolytes from polysulfide-bridged copolymers. Nano Energy 75, 104976 (2020).Article
CAS
Google Scholar
Sharon, D. et al. Intrinsic ion transport properties of block copolymer electrolytes. ACS Nano 14, 8902–8914 (2020).Article
CAS
PubMed
Google Scholar
Liu, D. et al. Enhancing ionic conductivity in tablet–bottlebrush block copolymer electrolytes with well-aligned nanostructures via solvent vapor annealing. J. Mater. Chem. C. 10, 4247–4256 (2022).Article
CAS
Google Scholar
Jia, D. et al. Multifunctional polymer bottlebrush-based gel polymer electrolytes for lithium metal batteries. Mater. Today Nano 15, 100128 (2021).Article
CAS
Google Scholar
Deng, C. T. et al. Role of molecular architecture on ion transport in ethylene oxide-based polymer electrolytes. Macromolecules 54, 2266–2276 (2021).Article
CAS
Google Scholar
Evans, C. M., Bridges, C. R., Sanoja, G. E., Bartels, J. & Segalman, R. A. Role of tethered ion placement on polymerized ionic liquid structure and conductivity: pendant versus backbone charge placement. ACS Macro Lett. 5, 925–930 (2016).Article
CAS
PubMed
Google Scholar
Sangoro, J. R. et al. Decoupling of ionic conductivity from structural dynamics in polymerized ionic liquids. Soft Matter 10, 3536–3540 (2014).Article
CAS
PubMed
Google Scholar
Jones, S. D. et al. Design of polymeric zwitterionic solid electrolytes with superionic lithium transport. ACS Cent. Sci. 8, 169–175 (2022).Article
CAS
PubMed
PubMed Central
Google Scholar
Leigh, T. & Fernandez-Trillo, P. Helical polymers for biological and medical applications. Nat. Rev. Chem. 4, 291–310 (2020).Article
CAS
PubMed
Google Scholar
Ekladious, I., Colson, Y. L. & Grinstaff, M. W. Polymer–drug conjugate therapeutics: advances, insights and prospects. Nat. Rev. Drug Discov. 18, 273–294 (2019).Article
CAS
PubMed
Google Scholar
Gao, Y. et al. Winding-locked carbon nanotubes/polymer nanofibers helical yarn for ultrastretchable conductor and strain sensor. ACS Nano 14, 3442–3450 (2020).Article
CAS
PubMed
Google Scholar
Wang, M. X. et al. Conductance-stable and integrated helical fiber electrodes toward stretchy energy storage and self-powered sensing utilization. Chem. Eng. J. 457, 141164 (2023).Article
CAS
Google Scholar
Liu, Y. S. et al. Controllable synthesis of Co@CoOx/helical nitrogen-doped carbon nanotubes toward oxygen reduction reaction as binder-free cathodes for Al–air batteries. ACS Appl. Mater. Interfaces 12, 16512–16520 (2020).Article
CAS
PubMed
Google Scholar
Zhao, M. Q. et al. Hierarchical vine-tree-like carbon nanotube architectures: in-situ CVD self-assembly and their use as robust scaffolds for lithium–sulfur batteries. Adv. Mater. 26, 7051–7058 (2014).Article
CAS
PubMed
Google Scholar
Jiang, Y. J. et al. ‘Metaphilic’ cell-penetrating polypeptide–vancomycin conjugate efficiently eradicates intracellular bacteria via a dual mechanism. ACS Cent. Sci. 6, 2267–2276 (2020).Article
CAS
PubMed
PubMed Central
Google Scholar
Jiang, Y., Chen, Y., Song, Z., Tan, Z. & Cheng, J. Recent advances in design of antimicrobial peptides and polypeptides toward clinical translation. Adv. Drug. Deliv. Rev. 170, 261–280 (2021).Article
CAS
PubMed
Google Scholar
Nguyen, T. P. et al. Polypeptide organic radical batteries. Nature 593, 61–66 (2021).Article
CAS
PubMed
Google Scholar
Lightfoot, P., Mehta, M. A. & Bruce, P. G. Crystal structure of the polymer electrolyte poly(ethylene oxide)3:LiCF3SO3. Science 262, 883–885 (1993).Article
CAS
PubMed
Google Scholar
Ma, Y. A., Shen, Y. & Li, Z. B. Different cell behaviors induced by stereochemistry on polypeptide brush grafted surfaces. Mater. Chem. Front. 1, 846–851 (2017).Article
CAS
Google Scholar
Papadopoulos, P., Floudas, G., Klok, H. A., Schnell, I. & Pakula, T. Self-assembly and dynamics of poly(γ-benzyl-l-glutamate) peptides. Biomacromolecules 5, 81–91 (2004).Article
CAS
PubMed
Google Scholar
Kricheldorf, H. R. & Mueller, D. Secondary structure of peptides. 3. Carbon-13 NMR cross polarization/magic angle spinning spectroscopic characterization of solid polypeptides. Macromolecules 16, 615–623 (1983).Article
CAS
Google Scholar
Tsutsumi, A. et al. Relaxation phenomena of poly-γ-benzyl-l-glutamate, poly-γ-methyl-l-glutamate, and copoly(γ-methyl-l-glutamate, γ-benzyl-l-glutamate). J. Macromol. Sci., B 8, 413–430 (1973).Article
Google Scholar
Evans, C. M., Sanoja, G. E., Popere, B. C. & Segalrnan, R. A. Anhydrous proton transport in polymerized ionic liquid block copolymers: roles of block length, ionic content, and confinement. Macromolecules 49, 395–404 (2016).Article
CAS
Google Scholar
Drozd-Rzoska, A., Rzoska, S. J. & Starzonek, S. New paradigm for configurational entropy in glass-forming systems. Sci. Rep. 12, 3058 (2022).Article
CAS
PubMed
PubMed Central
Google Scholar
Heres, M. et al. Ion transport in glassy polymerized ionic liquids: unraveling the impact of the molecular structure. Macromolecules 52, 88–95 (2019).Article
CAS
Google Scholar
Cheng, S. J. et al. Ionic aggregation in random copolymers containing phosphonium ionic liquid monomers. J. Polym. Sci. A1 50, 166–173 (2012).Article
CAS
Google Scholar
Hemp, S. T. et al. Comparing ammonium and phosphonium polymerized ionic liquids: thermal analysis, conductivity, and morphology. Macromol. Chem. Phys. 214, 2099–2107 (2013).Article
CAS
Google Scholar
Xia, Y. C. et al. Accelerated polymerization of N-carboxyanhydrides catalyzed by crown ether. Nat. Commun. 12, 732 (2021).Article
CAS
PubMed
PubMed Central
Google Scholar
Fan, F. et al. Effect of molecular weight on the ion transport mechanism in polymerized ionic liquids. Macromolecules 49, 4557–4570 (2016).Article
CAS
Google Scholar
Zhao, Q. J. & Evans, C. M. Effect of molecular weight on viscosity scaling and ion transport in linear polymerized ionic liquids. Macromolecules 54, 3395–3404 (2021).Article
CAS
Google Scholar
Keith, J. R., Mogurampelly, S., Aldukhi, F., Wheatle, B. K. & Ganesan, V. Influence of molecular weight on ion-transport properties of polymeric ionic liquids. Phys. Chem. Chem. Phys. 19, 29134–29145 (2017).Article
CAS
PubMed
Google Scholar
Timachova, K., Watanabe, H. & Balsara, N. P. Effect of molecular weight and salt concentration on ion transport and the transference number in polymer electrolytes. Macromolecules 48, 7882–7888 (2015).Article
CAS
Google Scholar
Han, S. et al. Sequencing polymers to enable solid-state lithium batteries. Nat. Mater. 22, 1515–1522 (2023).Article
CAS
PubMed
Google Scholar
Wada, A. Dielectric properties of polypeptide solutions. II. Relation between the electric dipole moment and the molecular weight of α helix. J. Chem. Phys. 30, 328–329 (1959).Article
CAS
Google Scholar
Choi, U. H. et al. Role of chain polarity on ion and polymer dynamics: molecular volume-based analysis of the dielectric constant for polymerized norbornene-based ionic liquids. Macromolecules 53, 10561–10573 (2020).Article
CAS
Google Scholar
Wilcox, K. G., Dingle, M. E., Saha, A., Hore, M. J. A. & Morozova, S. Persistence length of α-helical poly-l-lysine. Soft Matter 18, 6550–6560 (2022).Article
CAS
PubMed
Google Scholar
Choe, S. & Sun, S. X. The elasticity of α-helices. J. Chem. Phys. 122, 244912 (2005).Article
PubMed
Google Scholar
Papadopoulos, P. et al. Thermodynamic confinement and α-helix persistence length in poly(γ-benzyl-l-glutamate)-b-poly(dimethyl siloxane)-b-poly(γ-benzyl-l-glutamate) triblock copolymers. Biomacromolecules 7, 618–626 (2006).Article
CAS
PubMed
Google Scholar
Zhao, Q. J., Bennington, P., Nealey, P. F., Patel, S. N. & Evans, C. M. Ion specific, thin film confinement effects on conductivity in polymerized ionic liquids. Macromolecules 54, 10520–10528 (2021).Article
CAS
Google Scholar