Bates, C. M. & Bates, F. S. 50th Anniversary Perspective: block polymers—pure potential. Macromolecules 50, 3–22 (2017).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Lodge, T. P. Block copolymers: long-term growth with added value. Macromolecules 53, 2–4 (2020).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Bates, F. S. Polymer-polymer phase behavior. Science 251, 898–905 (1991).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Matsen, M. W. & Bates, F. S. Unifying weak- and strong-segregation block copolymer theories. Macromolecules 29, 1091–1098 (1996).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Gillard, T. M., Lee, S. & Bates, F. S. Dodecagonal quasicrystalline order in a diblock copolymer melt. Proc. Natl Acad. Sci. USA 113, 5167–5172 (2016).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Lee, S., Bluemle, M. J. & Bates, F. S. Discovery of a Frank-Kasper σ phase in sphere-forming block copolymer melts. Science 330, 349–353 (2010).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Kim, K. et al. Thermal processing of diblock copolymer melts mimics metallurgy. Science 356, 520–523 (2017).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Bates, M. W. et al. Stability of the A15 phase in diblock copolymer melts. Proc. Natl Acad. Sci. USA 116, 13194–13199 (2019).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Dorfman, K. D. Frank–Kasper phases in block polymers. Macromolecules 54, 10251–10270 (2021).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Matsen, M. W. Effect of architecture on the phase behavior of AB-type block copolymer melts. Macromolecules 45, 2161–2165 (2012).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Hsu, N.-W., Nouri, B., Chen, L.-T. & Chen, H.-L. Hexagonal close-packed sphere phase of conformationally symmetric block copolymer. Macromolecules 53, 9665–9675 (2020).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Lee, S., Leighton, C. & Bates, F. S. Sphericity and symmetry breaking in the formation of Frank–Kasper phases from one component materials. Proc. Natl Acad. Sci. USA 111, 17723–17731 (2014).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Matsen, M. W. Phase behavior of block copolymer/homopolymer blends. Macromolecules 28, 5765–5773 (1995).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Matsen, M. W. Polydispersity-induced macrophase separation in diblock copolymer Melts. Phys. Rev. Lett. 99, 148304 (2007).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Huang, Y.-Y., Chen, H.-L. & Hashimoto, T. Face-centered cubic lattice of spherical micelles in block copolymer/homopolymer blends. Macromolecules 36, 764–770 (2003).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Huang, Y.-Y., Hsu, J.-Y., Chen, H.-L. & Hashimoto, T. Existence of FCC-packed spherical micelles in diblock copolymer melt. Macromolecules 40, 406–409 (2007).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Chen, L., Lee, H. S. & Lee, S. Close-packed block copolymer Micelles induced by temperature quenching. Proc. Natl Acad. Sci. USA 115, 7218–7223 (2018).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Zhang, C. et al. Emergence of hexagonally close-packed spheres in linear block copolymer melts. J. Am. Chem. Soc. 143, 14106–14114 (2021).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Gan, Z. et al. Rationally leveraging polymer chain-length heterogeneity for robust structural engineering. CCS Chem https://doi.org/10.31635/ccschem.023.202303294 (2024)Sakurai, S. et al. Morphology reentry with a change in degree of chain asymmetry in neat asymmetric linear A1BA2 triblock copolymers. Macromolecules 50, 8647–8657 (2017).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Lodge, T. P., Wang, E., Zhu, J. & Bates, F. S. Solution and bulk structures of asymmetric PEP-PS-PEP′ triblock copolymers. Macromolecules 56, 6444–6451 (2023).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Zhou, D. et al. Precisely encoding geometric features into discrete linear polymer chains for robust structural engineering. J. Am. Chem. Soc. 143, 18744–18754 (2021).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Matsen, M. W. Equilibrium behavior of asymmetric ABA triblock copolymer melts. J. Chem. Phys. 113, 5539 (2000).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Takizawa, K., Tang, C. & Hawker, C. J. Molecularly defined caprolactone oligomers and polymers: synthesis and characterization. J. Am. Chem. Soc. 130, 1718–1726 (2008).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Barnes, J. C. et al. Iterative exponential growth of stereo- and sequence-controlled polymers. Nat. Chem. 7, 810–815 (2015).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
van Genabeek, B. et al. Synthesis and self-assembly of discrete dimethylsiloxane–lactic acid diblock co-oligomers: the dononacontamer and its shorter homologues. J. Am. Chem. Soc. 138, 4210–4218 (2016).ArticleÂ
PubMedÂ
Google ScholarÂ
Koo, M. B., Lee, S. W., Lee, J. M. & Kim, K. T. Iterative convergent synthesis of large cyclic polymers and block copolymers with discrete molecular weights. J. Am. Chem. Soc. 142, 14028–14032 (2020).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Gan, Z. et al. Local chain feature mandated self-assembly of block copolymers. J. Am. Chem. Soc. 145, 487–497 (2023).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
van Genabeek, B. et al. Properties and applications of precision oligomer materials; where organic and polymer chemistry join forces. J. Polym. Sci. 59, 373–403 (2021).ArticleÂ
Google ScholarÂ
Liu, M., Qiang, Y., Li, W., Qiu, F. & Shi, A.-C. Stabilizing the Frank-Kasper Phases via Binary Blends of AB Diblock Copolymers. ACS Macro Lett. 5, 1167–1171 (2016).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Chen, L.-T., Huang, Y.-T., Chen, C.-Y., Chen, M.-Z. & Chen, H.-L. Thermodynamically originated stacking fault in the close-packed structure of block copolymer micelles. Macromolecules 54, 8936–8945 (2021).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Ahn, J. et al. Continuous transition of colloidal crystals through stable random orders. Soft Matter 19, 3257–3266 (2023).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ
Matsen, M. W. Fast and accurate SCFT calculations for periodic block-copolymer morphologies using the spectral method with Anderson mixing. Eur. Phys. J. E 30, 361 (2009).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Grason, G. M. The packing of soft materials: molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts. Phys. Rep. 433, 1–64 (2006).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Shi, A.-C. Frustration in block copolymer assemblies. J. Phys. Condens Matter 33, 253001 (2021).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Xie, N., Li, W., Qiu, F. & Shi, A.-C. σ phase formed in conformationally asymmetric AB-type block copolymers. ACS Macro Lett. 3, 906–910 (2014).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Schulze, M. W. et al. Conformational asymmetry and quasicrystal approximants in Linear diblock copolymers. Phys. Rev. Lett. 118, 207801 (2017).ArticleÂ
ADSÂ
PubMedÂ
Google ScholarÂ
Zhou, D. et al. Discrete diblock copolymers with tailored conformational asymmetry: a precise model platform to explore complex spherical phases. Macromolecules 55, 7013–7022 (2022).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Cheong, G. K., Bates, F. S. & Dorfman, K. D. Symmetry breaking in particle-forming diblock polymer/homopolymer blends. Proc. Natl Acad. Sci. USA 117, 16764–16769 (2020).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
PubMed CentralÂ
Google ScholarÂ
Lindsay, A. P. et al. A15, σ, and a quasicrystal: access to complex particle packings via bidisperse diblock copolymer blends. ACS Macro Lett. 9, 197–203 (2020).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Mueller, A. J. et al. Emergence of a C15 laves phase in diblock polymer/homopolymer blends. ACS Macro Lett. 9, 576–582 (2020).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Sun, Y. et al. Quantify the contribution of chain length heterogeneity on block copolymer self-assembly. Giant 4, 100037 (2020).ArticleÂ
Google ScholarÂ
Ma, Z. et al. Modulation of the complex spherical packings through rationally doping a discrete homopolymer into a discrete block copolymer: a quantitative study. Macromolecules 55, 4331–4340 (2022).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Cai, D. et al. Effect of molecular architecture and symmetry on self-assembly: a quantitative revisit using discrete ABA triblock copolymers. ACS Macro Lett. 11, 555–561 (2022).ArticleÂ
CASÂ
PubMedÂ
Google ScholarÂ
Ma, Z. et al. Discrete linear–branched block copolymer with broken architectural symmetry. Macromolecules 56, 833–840 (2023).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Mau, S.-C. & Huse, D. A. Stacking entropy of hard-sphere crystals. Phys. Rev. E 59, 4396–4401 (1999).ArticleÂ
ADSÂ
CASÂ
Google ScholarÂ
Mahynski, N. A., Panagiotopoulos, A. Z., Meng, D. & Kumar, S. K. Stabilizing colloidal crystals by leveraging void distributions. Nat. Commun. 5, 4472 (2014).ArticleÂ
ADSÂ
CASÂ
PubMedÂ
Google ScholarÂ