Intermolecular C–H silylations of arenes and heteroarenes with mono-, bis-, and tris(trimethylsiloxy)hydrosilanes: control of silane redistribution under operationally diverse approaches

Chem. Sci., 2024, 15,11912-11918DOI: 10.1039/D4SC03394A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Noah Swann, Kiki Tang, Jihyeon Nam, Jooyeon Lee, Marek Domin, Thomas E. Shaw, Stosh A. Kozimor, Salina Som, Kangsang L. LeeOperationally diverse C–H silylations of (hetero) arenes with a broad silane scope are reported. The control of silane redistribution improves overall catalytic efficiency, affording the various arylsiloxysilanes useful for polysiloxane materials.The content of this RSS Feed (c) The Royal Society of Chemistry

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