Morphologies of polymer chains spun onto solid substrates

Balazs AC, Emrick T, Russell TP. Nanoparticle polymer composites: where two small worlds meet. Science. 2006;314:1107–10.Article 
CAS 
PubMed 

Google Scholar 
Rittigstein P, Priestley RD, Broadbelt LJ, Torkelson JM. Model polymer nanocomposites provide an understanding of confinement effects in real nanocomposites. Nat Mater. 2007;6:278–82.Article 
CAS 
PubMed 

Google Scholar 
Holt AP, Bocharova V, Cheng S, Kisliuk AM, White BT, Saito T, et al. Controlling interfacial dynamics: covalent bonding versus physical adsorption in polymer nanocomposites. ACS Nano. 2016;10:6843–52.Article 
CAS 
PubMed 

Google Scholar 
Bailey EJ, Winey KI. Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: a review. Prog Polym Sci. 2020;105:101242.Article 
CAS 

Google Scholar 
Morimune-Moriya S. Polymer/nanocarbon nanocomposites with enhanced properties. Polym J. 2022;54:977–84.Article 
CAS 

Google Scholar 
Miyata T, Kawagoe Y, Okabe T, Jinnai H. Morphologies of polymer chains adsorbed on inorganic nanoparticles in a polymer composite as revealed by atomic-resolution electron microscopy. Polym J. 2022;54:1297–306.Article 
CAS 

Google Scholar 
Morimitsu Y, Matsuno H, Oda Y, Yamamoto S, Tanaka K. Direct visualization of cooperative adsorption of a string-like molecule onto a solid. Sci Adv. 2022;8:eabn6349.Article 
CAS 
PubMed 
PubMed Central 

Google Scholar 
Fujigaya T. Development of polymer-wrapping methods for functionalization of carbon materials. Polym J. 2023;55:181–91.Article 
CAS 

Google Scholar 
Oyaizu K. Reversible and high-density energy storage with polymers populated with bistable redox sites. Polym J. 2024;56:127–44.Article 
CAS 

Google Scholar 
Yamaguchi A, Uematsu H, Sakaguchi T, Hashimoto T. Effects of different types of functionalized polypropylenes on the tensile strength of short carbon fiber-reinforced polypropylene composites. Polym J. 2024;56:205–14.Article 
CAS 

Google Scholar 
Awaja F, Gilbert M, Kelly G, Fox B, Pigram PJ. Adhesion of polymers. Prog Polym Sci. 2009;34:948–68.Article 
CAS 

Google Scholar 
Wei H, Xia J, Zhou W, Zhou L, Hussain G, Li Q, et al. Adhesion and cohesion of epoxy-based industrial composite coatings. Compos B Eng. 2020;193:108035.Article 
CAS 

Google Scholar 
Nobayashi M, Shikinaka K, Kaneko Y. Preparation of double-chain polysiloxane by template polymerization and the coexistence of water repellency and adhesion to glass in its cast film. Polym J. 2022;54:11–20.Article 
CAS 

Google Scholar 
Inutsuka M, Watanabe H, Aoyagi M, Yamada NL, Tanaka C, Ikehara T, et al. Effect of oligomer segregation on the aggregation state and strength at the polystyrene/substrate interface. ACS Macro Lett. 2022;11:504–9.Article 
CAS 
PubMed 

Google Scholar 
Gaire B, Wilson MC, Singla S, Dhinojwala A. Connection between molecular interactions and mechanical work of adhesion. ACS Macro Lett. 2022;11:1285–90.Article 
CAS 
PubMed 

Google Scholar 
Nguyen HK, Shundo A, Liang X, Yamamoto S, Tanaka K, Nakajima K. Unraveling nanoscale elastic and adhesive properties at the nanoparticle/epoxy interface using bimodal atomic force microscopy. ACS Appl Mater Interfaces. 2022;14:42713–22.Article 
CAS 
PubMed 

Google Scholar 
Xiao Z, Zhao Q, Niu Y, Zhao D. Adhesion advances: from nanomaterials to biomimetic adhesion and applications. Soft Matter. 2022;18:3447–64.Article 
CAS 
PubMed 

Google Scholar 
Barba BJD, Seko N, Madrid JF, Penaloza DP. Modified abaca fiber prepared by radiation-induced graft polymerization as a reinforcement for unsaturated polyester resin composites. Polym J. 2024;56:97–105.Article 
CAS 

Google Scholar 
Aragishi K, Takeda Y, Suzuki Y, Matsumoto A. Study on the deformation and fracture of epoxy monoliths through mechanical tensile and compressive tests and X-ray CT imaging. Polym J. 2024;56:529–40.Article 
CAS 

Google Scholar 
Aizawa M, Akiyama H, Matsuzawa Y, Shishido A. Reusable dismantlable adhesion interfaces induced by photodimerization and thermo/photocleavage reactions. Polym J. 2024;56:401–8.Article 
CAS 

Google Scholar 
de Gennes PG. Polymer solutions near an interface. 1. adsorption and depletion layers. Macromolecules. 1981;14:1637–44.Article 

Google Scholar 
Douglas JF, Johnson HE, Granick S. A simple kinetic model of polymer adsorption and desorption. Science. 1993;262:2010–2.Article 
CAS 
PubMed 

Google Scholar 
Hoeve CAJ, Dimarzio EA, Peyser P. Adsorption of polymer molecules at low surface coverage. J Chem Phys. 2004;42:2558.Article 

Google Scholar 
Napolitano S, Wübbenhorst M. The lifetime of the deviations from bulk behaviour in polymers confined at the nanoscale. Nat Commun. 2011;2:260.Article 

Google Scholar 
Lin EY, Frischknecht AL, Winey KI, Riggleman RA. Effect of surface properties and polymer chain length on polymer adsorption in solution. J Chem Phys. 2021;155:034701.Article 
CAS 
PubMed 

Google Scholar 
Hong Y, Li Y, Wang F, Zuo B, Wang X, Zhang L, Kawaguchi D, Tanaka K. Enhanced thermal stability of polystyrene by interfacial noncovalent interactions. Macromolecules. 2018;51:5620–27.Article 
CAS 

Google Scholar 
Morimitsu Y, Salatto D, Jiang N, Sen M, Nishitsuji S, Yavitt BM, et al. Structurally neutral” densely packed homopolymer-adsorbed chains for directed self-assembly of block copolymer thin films. Macromolecules. 2019;52:5157–67.Article 
CAS 

Google Scholar 
Yang DS, Chung K, Kim J. Controlled alignment of polymer chains near the semiconductor-dielectric interface. Org Electron. 2020;76:105484.Article 
CAS 

Google Scholar 
Saito M, Ito K, Yokoyama H. Negative interfacial energies of dynamic polymer brush interfaces: a discussion of the free energy balance. Polym J. 2023;55:897–902.Article 
CAS 

Google Scholar 
Yamane H, Oura M, Kawaguchi D, Nitta K, Sekizawa O, Ishikawa T, et al. Depth analysis of local conformation in poly(methyl methacrylate) adsorbed onto SiOx studied by soft X-ray absorption spectroscopy combined with an Ar gas cluster ion beam. Polym J. 2024;56:215–20.Article 
CAS 

Google Scholar 
Bansal A, Yang H, Li C, Cho K, Benicewicz BC, Kumar SK, et al. Quantitative equivalence between polymer nanocomposites and thin polymer films. Nat Mater. 2005;4:693–8.Article 
CAS 
PubMed 

Google Scholar 
Riggleman RA, Toepperwein G, Papakonstantopoulos GJ, Barrat J-L, de Pablo JJ. Entanglement network in nanoparticle reinforced polymers. J Chem Phys. 2009;130:244903.Article 
PubMed 

Google Scholar 
Krutyeva M, Wischnewski A, Monkenbusch M, Willner L, Maiz J, Mijangos C, et al. Effect of nanoconfinement on polymer dynamics: surface layers and interphases. Phys Rev Lett. 2013;110:1–5.
Google Scholar 
Popov I, Carroll B, Bocharova V, Genix A-C, Cheng S, Khamzin A, et al. Strong reduction in amplitude of the interfacial segmental dynamics in polymer nanocomposites. Macromolecules. 2020;53:4126–35.Article 
CAS 

Google Scholar 
Eguchi H, Hayashi H, Nagata K. Electrical conductivities and mechanical properties of porous cellulose nanofiber/reduced graphene oxide composites prepared with postreduction processes. Polym J. 2024;56:185–92.Article 
CAS 

Google Scholar 
Stickney PB, Falb RD. Carbon black-rubber interactions and bound rubber. Rubber Chem Technol. 1964;37:1299–340.Article 

Google Scholar 
Pliskin I, Tokita N. Bound rubber in elastomers: analysis of elastomer-filler interaction and its effect on viscosity and modulus of composite systems. J Appl Polym Sci. 1972;16:473–92.Article 
CAS 

Google Scholar 
Vondráček P, Schätz M. Bound rubber and “crepe hardening” in silicone rubber. J Appl Polym Sci. 1977;21:3211–22.Article 

Google Scholar 
Sugimoto S, Inutsuka M, Kawaguchi D, Tanaka K. The effect of interfacial dynamics on the bulk mechanical properties of rubber composites. Polym J. 2020;52:217–23.Article 
CAS 

Google Scholar 
Salatto D, Carrillo J-MY, Endoh MK, Taniguchi T, Yavitt BM, Masui T, et al. Structural and dynamical roles of bound polymer chains in rubber reinforcement. Macromolecules. 2021;54:11032–46.Article 
CAS 

Google Scholar 
Choi J, Hore MJA, Meth JS, Clarke N, Winey KI, Composto RJ. Universal scaling of polymer diffusion in nanocomposites. ACS Macro Lett. 2013;2:485–90.Article 
CAS 
PubMed 

Google Scholar 
Starr FW, Douglas JF, Meng D, Kumar SK. Bound layers “cloak” nanoparticles in strongly interacting polymer nanocomposites. ACS Nano. 2016;10:10960–5.Article 
CAS 
PubMed 

Google Scholar 
Forrest JA, Dalnoki-Veress K, Dutcher JR. Interface and chain confinement effects on the glass transition temperature of thin polymer films. Phys Rev E. 1997;56:5705–16.Article 
CAS 

Google Scholar 
Crosby AJ, Lee JY. Polymer nanocomposites: the “nano” effect on mechanical properties. Polym Rev. 2007;47:217–29.Article 
CAS 

Google Scholar 
Chen Z. Investigating buried polymer interfaces using sum frequency generation vibrational spectroscopy. Prog Polym Sci. 2010;35:1376–402.Article 
CAS 
PubMed 
PubMed Central 

Google Scholar 
Milchev A. Single-polymer dynamics under constraints: scaling theory and computer experiment. J Phys Condens Matter. 2011;23:103101.Article 
PubMed 

Google Scholar 
Hsu H-P, Binder K. Effect of chain stiffness on the adsorption transition of polymers. Macromolecules. 2013;46:2496–515.Article 
CAS 

Google Scholar 
Merling WL, Mileski JB, Douglas JF, Simmons DS. The glass transition of a single macromolecule. Macromolecules. 2016;49:7597–604.Article 
CAS 

Google Scholar 
Zuo B, Zhou H, Davis MJB, Wang X, Priestley RD. Effect of local chain conformation in adsorbed nanolayers on confined polymer molecular mobility. Phys Rev Lett. 2019;122:217801.Article 
CAS 
PubMed 

Google Scholar 
Huang J, Zhou J, Liu M. Interphase in polymer nanocomposites. JACS Au. 2022;2:280–91.Article 
CAS 
PubMed 
PubMed Central 

Google Scholar 
Scheutjens JMHM, Fleer GJ. Statistical theory of the adsorption of interacting chain molecules. 2. train, loop, and tail size distribution. J Phys Chem. 1980;84:178–90.Article 
CAS 

Google Scholar 
Lösche M, Schmitt J, Decher G, Bouwman WG, Kjaer K. Detailed structure of molecularly thin polyelectrolyte multilayer films on solid substrates as revealed by neutron reflectometry. Macromolecules. 1998;31:8893–906.Article 

Google Scholar 
Fujii Y, Yang Z, Leach J, Atarashi H, Tanaka K, Tsui OKC. Affinity of polystyrene films to hydrogen-passivated silicon and its relevance to the Tg of the films. Macromolecules. 2009;42:7418–22.Article 
CAS 

Google Scholar 
Gin P, Jiang N, Liang C, Taniguchi T, Akgun B, Satija SK, et al. Revealed architectures of adsorbed polymer chains at solid-polymer melt interfaces. Phys Rev Lett. 2012;109:265501.Article 
PubMed 

Google Scholar 
Füllbrandt M, Purohit PJ, Schönhals A. Combined FTIR and dielectric investigation of poly(vinyl acetate) adsorbed on silica particles. Macromolecules. 2013;46:4626–32.Article 

Google Scholar 
Fryer DS, Peters RD, Kim EJ, Tomaszewski JE, de Pablo JJ, Nealey PF, et al. Dependence of the glass transition temperature of polymer films on interfacial energy and thickness. Macromolecules. 2001;34:5627–34.Article 
CAS 

Google Scholar 
Tanaka K, Tateishi Y, Okada Y, Nagamura T, Doi M, Morita H. Interfacial mobility of polymers on inorganic solids. J Phys Chem B. 2009;113:4571–7.Article 
CAS 
PubMed 

Google Scholar 
Wong JSS, Hong L, Chul Bae S, Granick S. Polymer surface diffusion in the dilute limit. Macromolecules. 2011;44:3073–6.Article 
CAS 

Google Scholar 
Papon A, Montes H, Hanafi M, Lequeux F, Guy L, Saalwächter K. Glass-transition temperature gradient in nanocomposites: evidence from nuclear magnetic resonance and differential scanning calorimetry. Phys Rev Lett. 2012;108:65702.Article 

Google Scholar 
Inutsuka M, Horinouchi A, Tanaka K. Aggregation states of polymers at hydrophobic and hydrophilic solid interfaces. ACS Macro Lett. 2015;4:1174–8.Article 
CAS 
PubMed 

Google Scholar 
Wei T, Torkelson J. M. Molecular weight dependence of the glass transition temperature (Tg)-confinement effect in well-dispersed poly(2-vinyl pyridine)–silica nanocomposites: comparison of interfacial layer Tg and matrix Tg. Macromolecules. 2020;53:8725–36.Article 
CAS 

Google Scholar 
Uchida K, Mita K, Yamamoto S, Tanaka K. Conformational relaxation of ethylene-propylene-diene terpolymer at a solid interface. Polym J. 2023;55:683–90.Article 
CAS 

Google Scholar 
Yu C, Granick S. Revisiting polymer surface diffusion in the extreme case of strong adsorption. Langmuir. 2014;30:14538–44.Article 
CAS 
PubMed 

Google Scholar 
Sugimoto S, Inutsuka M, Kawaguchi D, Tanaka K. Reorientation kinetics of local conformation of polyisoprene at substrate interface. ACS Macro Lett. 2018;7:85–9.Article 
CAS 
PubMed 

Google Scholar 
Nguyen HK, Sugimoto S, Konomi A, Inutsuka M, Kawaguchi D, Tanaka K. Dynamics gradient of polymer chains near a solid interface. ACS Macro Lett. 2019;8:1006–11.Article 
CAS 
PubMed 

Google Scholar 
Tanaka K, Takahara A, Kajiyama T. Surface molecular motion in thin films of poly(styrene-block-methyl methacrylate) diblock copolymer. Acta Polym. 1995;46:476–82.Article 
CAS 

Google Scholar 
Kumaki J, Nishikawa Y, Hashimoto T. Visualization of single-chain conformations of a synthetic polymer with atomic force microscopy. J Am Chem Soc. 1996;118:3321–2.Article 
CAS 

Google Scholar 
Minko S, Kiriy A, Gorodyska G, Stamm M. Mineralization of single flexible polyelectrolyte molecules. J Am Chem Soc. 2002;124:10192–7.Article 
CAS 
PubMed 

Google Scholar 
Sheiko SS, Sun FC, Randall A, Shirvanyants D, Rubinstein M, Lee H, Il, et al. Adsorption-induced scission of carbon-carbon bonds. Nature 2006;440:191–4.Article 
CAS 
PubMed 

Google Scholar 
Kawaguchi D, Nishu T, Takano A, Matsushita Y. Direct observation of an isolated cyclic sodium poly(styrenesulfonate) molecule by atomic force microscopy. Polym J. 2007;39:271–5.Article 
CAS 

Google Scholar 
Anzai T, Kawauchi M, Kawauchi T, Kumaki J. Crystallization behavior of single isotactic poly(methyl methacrylate) chains visualized by atomic force microscopy. J Phys Chem B. 2015;119:338–47.Article 
CAS 
PubMed 

Google Scholar 
Oda Y, Kawaguchi D, Morimitsu Y, Yamamoto S, Tanaka K. Direct observation of morphological transition for an adsorbed single polymer chain. Sci Rep. 2020;10:20914.Article 
CAS 
PubMed 
PubMed Central 

Google Scholar 
Liang X. Visualization of nanomechanical properties of polymer composites using atomic force microscopy. Polym J. 2023;55:913–20.Article 
CAS 

Google Scholar 
Doi Y, Hara M, Seki T, Takano A, Ishida T, Uneyama T, et al. Preparation and characterization of two-dimensional sheet-shaped poly(methyl methacrylate) synthesized via γ-ray polymerization in nanoclay template. Polym J. 2023;55:957–65.Article 
CAS 

Google Scholar 
Ono M, Nakajima K. Influence of thermal treatment on the elastic modulus of a nano-dispersed elastomer domain in an injection-molded isotactic polypropylene/thermoplastic elastomer binary blend. Polym J. 2024;56:87–96.Article 
CAS 

Google Scholar 
Lederberg EM, Lederberg J. Genetic studies of lysogenicity in Escherichia coli. Genetics. 1953;38:51.Article 
CAS 
PubMed 
PubMed Central 

Google Scholar 
Saenger W. Principles of nucleic acid structure. 1st ed. New York: Springer-Verlag; (1984).Netz HH, Orland H. Variational charge renormalization in charged systems. EPJ E. 2003;11:301–11.CAS 

Google Scholar 
Guilbaud S, Salomé L, Destainville N, Manghi M, Tardin C. Dependence of DNA persistence length on ionic strength and ion type. Phys Rev Lett. 2019;122:1–6.Article 

Google Scholar 
Harris, Millman CR, van der Walt KJ, Gommers R SJ, Virtanen P, Cournapeau D, et al. Array programming with NumPy. Nature. 2020;585:357–62.Article 
CAS 
PubMed 
PubMed Central 

Google Scholar 
Bradski G. The OpenCV library. Dr Dobbs J Softw Tools. 2000;120:122–5.
Google Scholar 
Brostow W, Drewniak M. Computer simulations of chain conformations in dilute polymer solutions under shear flow. J Chem Phys. 1996;105:7135–9.Article 
CAS 

Google Scholar 
Jiménez J. Near-wall turbulence. Phys Fluids. 2013;25:101302.Article 

Google Scholar 

Hot Topics

Related Articles