The industrial production of nylon 6 usually includes synthesizing caprolactam through the cyclohexanone–hydroxylamine route. This approach requires complex protocols, elevated temperatures, noble metal catalysts and the use of hazardous strong acids or hydroxylamine. Additionally, a significant quantity of ammonium sulphate is generated during the synthesis procedure. This study aims to develop an electrochemical reduction system for the conversion of ADN generated from the electrolytic dimerization of acrylonitrile (AN) to 6-aminocapronitrile (ACN), a precursor of nylon 6. This system utilizes a cost-effective Cu nanomaterial under eco-friendly conditions, avoiding lengthy and harsh processes, eliminating NH2OH use, and reducing low-value ammonium sulfate generation. This electrosynthesis method maintains approximately 85% ACN selectivity at 40–100 mA cm−2 when passing the charge required for 37% theoretical conversion. When extending the reaction time to achieve an 80% conversion, ACN selectivity still reached 81.6%, exceeding the theoretical value of non-selective hydrogenation by 20%. The pseudo-first-order reaction kinetic modeling proves that the reaction rate constant for ADN hydrogenation is significantly greater than that for ACN hydrogenation, highlighting the selectivity advantage of the system for ACN. This study establishes the foundation for developing a continuous electrolysis process to produce the nylon 6 precursor from AN feedstock.
This article is Open Access
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