Local electric field in nanocavities dictates the vibrational relaxation dynamics of interfacial molecules

Chem. Sci., 2024, 15,11507-11514DOI: 10.1039/D4SC02463J, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xiaoxuan Zheng, Quanbing Pei, Junjun Tan, Shiyu Bai, Yi Luo, Shuji YeThe electric field sensed by molecules in nanocavities determines the molecular vibrational energy relaxation dynamics using ultrafast time-resolved sum frequency generation vibrational spectroscopy.The content of this RSS Feed (c) The Royal Society of Chemistry