Tandem catalytic allylic C–H amination and asymmetric [2,3]-rearrangement via bimetallic relay catalysis

Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC03315A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhenwei Wu, Xi Yang, Fangqing Zhang, Yangbin Liu, Xiaoming FengAn asymmetric tandem allylic C–H amination and [2,3]-sigmatropic rearrangement has been developed by making use of bimetallic relay catalysis with an achiral Pd(0) catalyst and a chiral N,N′-dioxide-Mg(II) complex.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry