2D hexagonal assembly of a dipolar rotor with a close interval of 0.8 nm using a triptycene-based supramolecular scaffold

Chem. Sci., 2024, 15,11021-11028DOI: 10.1039/D4SC02750G, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takejiro Ogawa, Fumitaka Ishiwari, Fatin Hajjaj, Yoshiaki Shoji, Takashi Kajitani, Koji Yazawa, Takahiro Ohkubo, Takanori FukushimaA triptycene-based supramolecular scaffold allowed the 2D assembly of dipolar rotors at close intervals of 0.8 nm. Solid-state 19F-MAS NMR measurements revealed that the rotors in the assembly have motility with a low activation barrier.The content of this RSS Feed (c) The Royal Society of Chemistry

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