Nitrogen monoxide and calix[4]pyrrolato aluminate: structural constraint enabled NO dimerization

Chem. Sci., 2024, 15,10803-10809DOI: 10.1039/D4SC02378A, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Senta J. Kohl, Lukas M. Sigmund, Manuel Schmitt, Lutz GrebThe dimerization of nitrogen monoxide (NO) is highly relevant in biochemical and environmental redox processes. Here, it is shown how structral constraint and element-ligand cooperativity can steer this reaction.The content of this RSS Feed (c) The Royal Society of Chemistry