Verbena officinalis (VO) leaf extract as an anti-corrosion inhibitor for carbon steel in acidic environment

Fouda, A. S., Abd El-Maksoud, S. A., Belal, A. A. M., El-Hossiany, A. & Ibrahim, A. Effectiveness of some organic compounds as corrosion inhibitors for stainless steel 201 in 1M HCl: Experimental and theoretical studies. Int. J. Electrochem. Sci. 13, 9826–9846. https://doi.org/10.20964/2018.10.36 (2018).Article 
CAS 

Google Scholar 
Fouda, A. S., Rashwan, S., El-Hossiany, A. & El-Morsy, F. E. Corrosion inhibition of zinc in hydrochloric acid solution using some organic compounds as eco-friendly inhibitors. J. Chem. Biol. Phys. Sci. 9, 1–24. https://doi.org/10.24214/jcbps.A.9.1.00124 (2019).Article 
CAS 

Google Scholar 
Khaled, M. A., Ismail, M. A. & Fouda, A. E. S. Novel pyrimidine-bichalcophene derivatives as corrosion inhibitors for copper in 1 M nitric acid solution. 25314–25333 (2021). https://doi.org/10.1039/d1ra03603c.Quraishi, M. A. & Sardar, R. Dithiazolidines—A new class of heterocyclic inhibitors for prevention of mild steel corrosion in hydrochloric acid solution. Corrosion 58, 103–107. https://doi.org/10.5006/1.3277308 (2002).Article 
CAS 

Google Scholar 
Li, X., Xie, X., Deng, S. & Du, G. Two phenylpyrimidine derivatives as new corrosion inhibitors for cold rolled steel in hydrochloric acid solution. Corros. Sci. 87, 27–39. https://doi.org/10.1016/j.corsci.2014.05.017 (2014).Article 
ADS 
CAS 

Google Scholar 
Tabesh, R. N., Abdel-Gaber, A. M., Hammud, H. H. & Al-Oweini, R. Inhibition of steel corrosion in sulfuric acid solution by 1, 10-phenanthroline, para-aminobenzoate and their corresponding manganese complex. Zeitschrift für Phys. Chemie 233, 1553–1569. https://doi.org/10.1515/zpch-2018-1254 (2019).Article 
CAS 

Google Scholar 
Verma, C., Olasunkanmi, L. O., Ebenso, E. E. & Quraishi, M. A. Substituents effect on corrosion inhibition performance of organic compounds in aggressive ionic solutions: A review. J. Mol. Liq. 251, 100–118. https://doi.org/10.1016/j.molliq.2017.12.055 (2018).Article 
CAS 

Google Scholar 
Verma, C., Ebenso, E. E. & Quraishi, M. A. Corrosion inhibitors for ferrous and non-ferrous metals and alloys in ionic sodium chloride solutions: A review. J. Mol. Liq. 248, 927–942. https://doi.org/10.1016/j.molliq.2017.10.094 (2017).Article 
CAS 

Google Scholar 
Singh, P., Makowska-Janusik, M., Slovensky, P. & Quraishi, M. A. Nicotinonitriles as green corrosion inhibitors for mild steel in hydrochloric acid: Electrochemical, computational and surface morphological studies. J. Mol. Liq. 220, 71–81. https://doi.org/10.1016/j.molliq.2016.04.042 (2016).Article 
CAS 

Google Scholar 
Hinton, B. R. W. Corrosion prevention and control. Handb. Phys. Chem. rare earths 21, 29–92 (1995).https://doi.org/10.1016/S0168-1273(05)80109-6El-Tabesh, R. N., Abdel-Gaber, A. M., Hammud, H. H. & Oweini, R. Effect of mixed-ligands copper complex on the corrosion inhibition of carbon steel in sulfuric acid solution. J. Bio-and Tribo-Corros. 6, 1–8. https://doi.org/10.1007/s40735-020-0323-8 (2020).Article 

Google Scholar 
Umoren, S. A. & Eduok, U. M. Application of carbohydrate polymers as corrosion inhibitors for metal substrates in different media: A review. Carbohydr. Polym. 140, 314–341. https://doi.org/10.1016/j.carbpol.2015.12.038 (2016).Article 
CAS 
PubMed 

Google Scholar 
Hu, K. et al. Effect of novel cytosine-l-alanine derivative based corrosion inhibitor on steel surface in acidic solution. J. Mol. Liq. 222, 109–117. https://doi.org/10.1016/j.molliq.2016.07.008 (2016).Article 
ADS 
CAS 

Google Scholar 
Dakhil, R. M., Gaaz, T. S., Al-Amiery, A. A. & Kadhum, A. A. H. Inhibitive impacts extract of Citrus aurantium leaf of carbon steel in corrosive media. Green Chem. Lett. Rev. 11, 559–566. https://doi.org/10.1080/17518253.2018.1547796 (2018).Article 
CAS 

Google Scholar 
Raghavendra, N. Latest exploration on natural corrosion inhibitors for industrial important metals in hostile fluid environments: A comprehensive overview. J. Bio-and Tribo-Corros. 5, 54. https://doi.org/10.1007/s40735-019-0240-x (2019).Article 

Google Scholar 
Ji, G., Anjum, S., Sundaram, S. & Prakash, R. Musa paradisica peel extract as green corrosion inhibitor for mild steel in HCl solution. Corros. Sci. 90, 107–117. https://doi.org/10.1016/j.corsci.2014.10.002 (2015).Article 
CAS 

Google Scholar 
Shainy, K. M., Ammal, P. R., Unni, K. N., Benjamin, S. & Joseph, A. Surface interaction and corrosion inhibition of mild steel in hydrochloric acid using pyoverdine, an eco-friendly bio-molecule. J. Bio-and Tribo-Corros. 2, 1–12. https://doi.org/10.1007/s40735-016-0050-3 (2016).Article 

Google Scholar 
Fouda, A. S., Shalabi, K. & E-Hossiany, A. Moxifloxacin antibiotic as green corrosion inhibitor for carbon steel in 1 M HCl. J. Bio-and Tribo-Corros. 2, 1–13. https://doi.org/10.1007/s40735-016-0048-x (2016).Article 

Google Scholar 
Arthur, D. E. & Abechi, S. E. Corrosion inhibition studies of mild steel using Acalypha chamaedrifolia leaf extract in hydrochloric acid medium. SN Appl. Sci. 1, 1–11. https://doi.org/10.1007/s42452-019-1138-4 (2019).Article 
CAS 

Google Scholar 
Pal, A. & Das, C. A novel use of solid waste extract from tea factory as corrosion inhibitor in acidic media on boiler quality steel. Ind. Crop. Prod. 151, 112468. https://doi.org/10.1016/j.indcrop.2020.112468 (2020).Article 
CAS 

Google Scholar 
Khayatkashani, M. et al. Insight into the corrosion inhibition of Biebersteinia multifida root extract for carbon steel in acidic medium. Sci. Total Environ. 836, 155527. https://doi.org/10.1016/j.scitotenv.2022.155527 (2022).Article 
CAS 
PubMed 

Google Scholar 
Haldhar, R., Prasad, D., Bahadur, I., Dagdag, O. & Berisha, A. Evaluation of Gloriosa superba seeds extract as corrosion inhibition for low carbon steel in sulfuric acidic medium: A combined experimental and computational studies. J. Mol. Liq. 323, 114958. https://doi.org/10.1016/j.molliq.2020.114958 (2021).Article 
CAS 

Google Scholar 
Naderi, R., Bautista, A., Velasco, F., Soleimani, M. & Pourfath, M. Use of licorice plant extract for controlling corrosion of steel rebar in chloride-polluted concrete pore solution. J. Mol. Liq. 346, 117856. https://doi.org/10.1016/j.molliq.2021.117856 (2022).Article 
CAS 

Google Scholar 
Al Hasan, N. H. J., Alaradi, H. J., Al Mansor, Z. A. K. & Al Shadood, A. H. J. The dual effect of stem extract of Brahmi (Bacopamonnieri) and Henna as a green corrosion inhibitor for low carbon steel in 0.5 M NaOH solution. Case Stud. Constr. Mater. 11, e00300. https://doi.org/10.1016/j.cscm.2019.e00300 (2019).Article 

Google Scholar 
Gayakwad, N., Patil, V. & Rao, B. M. The effect of Rhoeo discolor plant leaf extract on mild steel of corrosion inhibition in acid media. Mater. Today Proc. 49, 536–541. https://doi.org/10.1016/j.mtsust.2023.100373 (2022).Article 
CAS 

Google Scholar 
Fekri, M. H., Omidali, F., Alemnezhad, M. M. & Ghaffarinejad, A. Turnip peel extract as green corrosion bio-inhibitor for copper in 3.5% NaCl solution. Mater. Chem. Phys. 286, 126150. https://doi.org/10.1016/j.matchemphys.2022.126150 (2022).Article 
CAS 

Google Scholar 
Fernine, Y. et al. Anti-corrosion performance of Ocimum basilicum seed extract as environmental friendly inhibitors for mild steel in HCl solution: Evaluations of electrochemical, EDX, DFT and Monte Carlo. J. Mol. Liq. 355, 118867. https://doi.org/10.1016/j.molliq.2022.118867 (2022).Article 
CAS 

Google Scholar 
Alvarez, P. E. et al. Improved electrochemical strategy to characterize adsorption and corrosion inhibition related to biomolecules from plant extracts: The case of Annona cherimola. Results Chem. 4, 100233. https://doi.org/10.1016/j.rechem.2021.100233 (2022).Article 
CAS 

Google Scholar 
Bhardwaj, N., Sharma, P., Singh, K., Rana, D. & Kumar, V. Phyllanthus emblica seed extract as corrosion inhibitor for stainless steel used in petroleum industry (SS-410) in acidic medium. Chem. Phys. Impact 3, 100038. https://doi.org/10.1016/j.chphi.2021.100038 (2021).Article 

Google Scholar 
Asadi, N., Ramezanzadeh, M., Bahlakeh, G. & Ramezanzadeh, B. Utilizing Lemon Balm extract as an effective green corrosion inhibitor for mild steel in 1M HCl solution: A detailed experimental, molecular dynamics, Monte Carlo and quantum mechanics study. J. Taiwan Inst. Chem. Eng. 95, 252–272. https://doi.org/10.1016/j.jtice.2018.07.011 (2019).Article 
CAS 

Google Scholar 
de Lima, KCdeS. et al. Glycine max meal extracts as corrosion inhibitor for mild steel in sulphuric acid solution. J. Mater. Res. Technol. 9, 12756–12772. https://doi.org/10.1016/j.jmrt.2020.09.019 (2020).Article 
CAS 

Google Scholar 
Fernandes, F. D., Ferreira, L. M. & Da Silva, M. Application of Psidium guajava L. leaf extract as a green corrosion inhibitor in biodiesel: Biofilm formation and encrustation. Appl. Surf. Sci. Adv. 6, 100185. https://doi.org/10.1016/j.apsadv.2021.100185 (2021).Article 

Google Scholar 
Prifiharni, S. et al. Extract sarampa wood (Xylocarpus Moluccensis) as an eco-friendly corrosion inhibitor for mild steel in HCl 1M. J. Indian Chem. Soc. 99, 100520. https://doi.org/10.1016/j.apsadv.2021.100185 (2022).Article 
CAS 

Google Scholar 
Devikala, S., Kamaraj, P., Arthanareeswari, M. & Patel, M. B. Green corrosion inhibition of mild steel by aqueous Allium sativum extract in 3.5% NaCl. Mater. Today Proc. 14, 580–589. https://doi.org/10.1016/J.MATPR.2019.04.182 (2019).Article 
CAS 

Google Scholar 
Muthukrishnan, P., Prakash, P., Ilayaraja, M., Jeyaprabha, B. & Shankar, K. Effect of acidified feronia elephantum leaf extract on the corrosion behavior of mild steel. Metall. Mater. Trans. B 46, 1448–1460. https://doi.org/10.1007/s11663-015-0322-1 (2015).Article 
CAS 

Google Scholar 
Muthukrishnan, P., Saravana Kumar, K., Jeyaprabha, B. & Prakash, P. Anticorrosive activity of Kigelia pinnata leaf extract on mild steel in acidic media. Metall. Mater. Trans. A 45, 4510–4524. https://doi.org/10.1007/s11661-014-2366-2 (2014).Article 
CAS 

Google Scholar 
Genc, Y., Dereli, F. T. G., Saracoglu, I. & Akkol, E. K. The inhibitory effects of isolated constituents from Plantago major subsp. major L. on collagenase, elastase and hyaluronidase enzymes: Potential wound healer. Saudi Pharm. J. 28, 101–106. https://doi.org/10.1016/j.jsps.2019.11.011 (2020).Article 
CAS 
PubMed 

Google Scholar 
Kawashty, S. A. & El-Garf, I. A. The flavonoid chemosystematics of Egyptian Verbena species. Biochem. Syst. Ecol. 28, 919–921. https://doi.org/10.1016/s0305-1978(99)00114-3 (2000).Article 
CAS 
PubMed 

Google Scholar 
Elgyar, O. A., Ouf, A. M., El-Hossiany, A. & Fouda, A. E. A. S. The inhibition action of viscum album extract on the corrosion of carbon steel in hydrochloric acid solution. Biointerface Res. Appl. Chem. 11, 14344–14358. https://doi.org/10.33263/BRIAC116.1434414358 (2021).Article 
CAS 

Google Scholar 
Fouda, A. S., Eissa, M. & El-Hossiany, A. Ciprofloxacin as eco-friendly corrosion inhibitor for carbon steel in hydrochloric acid solution. Int. J. Electrochem. Sci. 13, 11096–11112. https://doi.org/10.20964/2018.11.86 (2018).Article 
CAS 

Google Scholar 
Fouda, A. S., Ahmed, R. E. & El-Hossiany, A. Chemical, electrochemical and quantum chemical studies for famotidine drug as a safe corrosion inhibitor for α-brass in HCl solution. Prot. Met. Phys. Chem. Surf. 57, 398–411. https://doi.org/10.1134/S207020512101010X (2021).Article 
CAS 

Google Scholar 
Ibrahim, M. B., Sulaiman, Z., Usman, B. & Ibrahim, M. A. Effect of Henna Leaf on the Corrosion Inhibitor of Tin in Acidic and Alkaline Media. World 4, 45–51. https://doi.org/10.11648/j.wjac.20190404.11 (2019).Article 

Google Scholar 
Seyam, D. F., Tantawy, A. H., Eid, S. & El-Etre, A. Y. Study of the inhibition effect of two novel synthesized amido-amine-based cationic surfactants on aluminum corrosion in 0.5 M HCl solution. J. Surfactants Deterg. 25, 133–143. https://doi.org/10.3390/molecules28114540 (2022).Article 
CAS 

Google Scholar 
Frumkin, A. N. Surface tension curves of higher fatty acids and the equation of condition of the surface layer. Z. Phys. Chem 116, 466–484 (1925).Article 
CAS 

Google Scholar 
Eid, S. Expired Desloratidine drug as inhibitor for corrosion of carbon steel pipeline in hydrochloric acid solution. Int. J. Electrochem. Sci. 16, 150852. https://doi.org/10.20964/2021.01.27 (2021).Article 
CAS 

Google Scholar 
Donahue, F. M. & Nobe, K. Theory of organic corrosion inhibitors: Adsorption and linear free energy relationships. J. Electrochem. Soc. 112, 886. https://doi.org/10.1149/1.2423723 (1965).Article 
ADS 
CAS 

Google Scholar 
Khamis, E., Bellucci, F., Latanision, R. M. & El-Ashry, E. S. H. Acid corrosion inhibition of nickel by 2-(triphenosphoranylidene) succinic anhydride. Corrosion 47, 677–686. https://doi.org/10.5006/1.3585307 (1991).Article 
CAS 

Google Scholar 
Zarrouk, A., Hammouti, B., Zarrok, H., Al-Deyab, S. S. & Messali, M. Temperature effect, activation energies and thermodynamic adsorption studies of L-cysteine methyl ester hydrochloride as copper corrosion inhibitor in nitric acid 2M. Int. J. Electrochem. Sci 6, 6261–6274. https://doi.org/10.1016/S1452-3981(23)19679-9 (2011).Article 
CAS 

Google Scholar 
Gupta, R. K., Malviya, M., Verma, C. & Quraishi, M. A. Aminoazobenzene and diaminoazobenzene functionalized graphene oxides as novel class of corrosion inhibitors for mild steel: Experimental and DFT studies. Mater. Chem. Phys. 198, 360–373. https://doi.org/10.1016/j.matchemphys.2017.06.030 (2017).Article 
CAS 

Google Scholar 
Akande, I. G., Oluwole, O. O. & Fayomi, O. S. I. Optimizing the defensive characteristics of mild steel via the electrodeposition of ZnSi3N4 reinforcing particles. Def. Technol. 15, 526–532. https://doi.org/10.1016/j.dt.2018.11.001 (2019).Article 

Google Scholar 
Fouda, A. S., El-Gharkawy, E.-S., Ramadan, H. & El-Hossiany, A. Corrosion resistance of mild steel in hydrochloric acid solutions by clinopodium acinos as a green inhibitor. Biointerface Res. Appl. Chem. 11, 9786. https://doi.org/10.33263/BRIAC112.97869803 (2021).Article 
CAS 

Google Scholar 
Li, W., He, Q., Zhang, S., Pei, C. & Hou, B. Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium. J. Appl. Electrochem. 38, 289–295. https://doi.org/10.1007/s10800-007-9437-7 (2008).Article 
CAS 

Google Scholar 
Elayyachy, M., El Idrissi, A. & Hammouti, B. New thio-compounds as corrosion inhibitor for steel in 1 M HCl. Corros. Sci. 48, 2470–2479. https://doi.org/10.1016/j.corsci.2005.09.016 (2006).Article 
CAS 

Google Scholar 
Abdel-Gaber, A. M., Abd-El-Nabey, B. A. & Saadawy, M. The role of acid anion on the inhibition of the acidic corrosion of steel by lupine extract. Corros. Sci. 51, 1038–1042. https://doi.org/10.1016/j.corsci.2009.03.003 (2009).Article 
CAS 

Google Scholar 
Sastri, V. S. Green Corrosion Inhibitors: Theory and Practice (John Wiley & Sons, 2012). https://doi.org/10.1002/9781118015438.Book 

Google Scholar 
Wang, H., Shi, H., Jepson, W. P., Hong, T. & Kang, C. Characterization of inhibitor and corrosion product film using electrochemical impedance spectroscopy (EIS). In CORROSION 2001 (OnePetro, 2001).Rengamani, S., Muralidharan, S., Anbu Kulandainathan, M. & Venkatakrishna Iyer, S. Inhibiting and accelerating effects of aminophenols on the corrosion and permeation of hydrogen through mild steel in acidic solutions. J. Appl. Electrochem. 24, 355–360. https://doi.org/10.1007/BF00242066 (1994).Article 
CAS 

Google Scholar 
Hegazy, M. A., Rashwan, S. M., Kamel, M. M. & El Kotb, M. S. Synthesis, surface properties and inhibition behavior of novel cationic gemini surfactant for corrosion of carbon steel tubes in acidic solution. J. Mol. Liq. 211, 126–134. https://doi.org/10.1016/j.molliq.2015.06.051 (2015).Article 
CAS 

Google Scholar 
Li, X., Deng, S. & Fu, H. Triazolyl blue tetrazolium bromide as a novel corrosion inhibitor for steel in HCl and H2SO4 solutions. Corros. Sci. 53, 302–309. https://doi.org/10.1016/j.corsci.2010.09.036 (2011).Article 
CAS 

Google Scholar 
Banerjee, G. & Malhotra, S. N. Contribution to adsorption of aromatic amines on mild steel surface from HCl solutions by impedance, UV, and Raman spectroscopy. Corrosion 48, 10–15. https://doi.org/10.5006/1.3315912 (1992).Article 
CAS 

Google Scholar 
Wahdan, M. H., Hermas, A. A. & Morad, M. S. Corrosion inhibition of carbon-steels by propargyltriphenylphosphonium bromide in H2SO4 solution. Mater. Chem. Phys. 76, 111–118. https://doi.org/10.1016/S0254-0584(01)00526-0 (2002).Article 
CAS 

Google Scholar 
Lebrini, M., Lagrenee, M., Vezin, H., Gengembre, L. & Bentiss, F. Electrochemical and quantum chemical studies of new thiadiazole derivatives adsorption on mild steel in normal hydrochloric acid medium. Corros. Sci. 47, 485–505. https://doi.org/10.1016/j.corsci.2004.06.001 (2005).Article 
CAS 

Google Scholar 
Niu, L. et al. Corrosion inhibition of iron in acidic solutions by alkyl quaternary ammonium halides: Correlation between inhibition efficiency and molecular structure. Appl. Surf. Sci. 252, 1634–1642. https://doi.org/10.1016/j.apsusc.2005.02.134 (2005).Article 
ADS 
CAS 

Google Scholar