Total synthesis of dissectol A, using an enediolate-based Tsuji–Trost reaction

Chem. Sci., 2024, 15,10541-10546DOI: 10.1039/D4SC01745E, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ruben L. H. Andringa, Nittert Marinus, Daan V. Bunt, Elizabeth R. Haiderer, Robert B. Abramovitch, Christopher D. Brown, Kyu Y. Rhee, Martin D. Witte, Adriaan J. MinnaardThe densely functionalized terpene glycoside dissectol A has been prepared via site-selective oxidation and an intramolecular Tsuji–Trost allylic alkylation reaction with an enediolate as the nucleophile.The content of this RSS Feed (c) The Royal Society of Chemistry

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