Streamlined synthetic assembly of α-chiral CAAC ligands and catalytic performance of their copper and ruthenium complexes

Chem. Sci., 2024, 15,13864-13871DOI: 10.1039/D4SC04278F, Edge Article Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Adrien Madron du Vigné, Nicolai CramerA streamlined strategy to diastereo- and enantiomerically pure α,β-chiral CAAC salts and their corresponding transition metal complexes is reported, displaying high enantioselectivities in benchmark asymmetric transformations.The content of this RSS Feed (c) The Royal Society of Chemistry