Gu, Q., Jia, Q., Long, J. & Gao, Z. Heterogeneous photocatalyzed C−C cross‐coupling reactions under visible-light and near-infrared light irradiation. ChemCatChem 11, 669–683 (2018).Article
Google Scholar
Ren, T. Peripheral covalent modification of inorganic and organometallic compounds through C-C bond formation reactions. Chem. Rev. 108, 4185–4207 (2008).Article
CAS
PubMed
Google Scholar
Mizoroki, T., Mori, K. & Ozaki, A. Arylation of olefin with aryl iodide catalyzed by palladium. Bull. Chem. Soc. Jpn. 44, 581 (1971).Article
CAS
Google Scholar
Heck, R. F. & Nolley, J. P. Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides. J. Org. Chem. 37, 2320–2322 (1972).Article
CAS
Google Scholar
Song, C. E., Oh, C. R., Roh, E. J., Lee, S.-G. & Choi, J. H. One-step synthesis of paclitaxel side-chain precursor: benzamide-based asymmetric aminohydroxylation of isopropyl trans-cinnamate. Tetrahedron Asymm. 10, 671–674 (1999).Article
CAS
Google Scholar
Jing, L., Jin, Y., Zhang, S. & Sun, X. Synthesis of anticancer drug docetaxel. Chin. J. Med. Chem. 16, 292–295 (2006).CAS
Google Scholar
Matsuura, T., Overman, L. E. & Poon, D. J. Catalytic asymmetric synthesis of either enantiomer of the calabaralkaloids physostigmine and physovenine. J. Am. Chem. Soc. 120, 6500–6503 (1998).Article
CAS
Google Scholar
Sato, Y., Sodeoka, M. & Shibasaki, M. Catalytic asymmetric carbon-carbon bond formation: asymmetric synthesis of cis-decalin derivatives by palladium-catalyzed cyclization of prochiral alkenyl iodides. J. Org. Chem. 54, 4738–4739 (1989).Article
CAS
Google Scholar
Herrmann, W. A., Elison, M., Fischer, J., Köcher, C. & Artus, G. R. J. Metal complexes of N‐heterocyclic carbenes—a new structural principle for catalysts in homogeneous catalysis. Angew. Chem. Int. Ed. 34, 2371–2374 (1995).Article
CAS
Google Scholar
Tulloch, A. A. D. et al. Pyridine functionalised N-heterocyclic carbene complexes of palladium. Chem. Commun. 1247–1248, https://doi.org/10.1039/b002645j (2000)Kampwerth, A., Terhorst, M., Kampling, N., Vogt, D. & Seidensticker, T. Synthesis of biobased amines via Pd-catalysed telomerisation of the renewable β-myrcene in a water/ethanol multiphase system: catalyst recycling enabled by a self-separating product phase. Green Chem. 25, 6345–6354 (2023).Article
CAS
Google Scholar
Chatzopoulou, M. et al. Pilot study to quantify palladium impurities in lead-like compounds following commonly used purification techniques. ACS Med. Chem. Lett. 13, 262–270 (2022).Article
CAS
PubMed
PubMed Central
Google Scholar
Wang, C., Xie, Z., deKrafft, K. E. & Lin, W. Doping metal-organic frameworks for water oxidation, carbon dioxide reduction, and organic photocatalysis. J. Am. Chem. Soc. 133, 13445–13454 (2011).Article
CAS
PubMed
Google Scholar
Choe, K. et al. Fast and selective semihydrogenation of alkynes by palladium nanoparticles sandwiched in metal–organic frameworks. Angew. Chem. Int. Ed. 59, 3650–3657 (2020).Article
CAS
Google Scholar
Lim, J. et al. Amine-tagged fragmented ligand installation for covalent modification of MOF-74. Angew. Chem. Int. Ed. 60, 9296–9300 (2021).Article
CAS
Google Scholar
Martínez-Izquierdo, L., Téllez, C. & Coronas, J. Highly stable Pebax® Renew® thin-film nanocomposite membranes with metal organic framework ZIF-94 and ionic liquid [Bmim][BF4] for CO2 capture. J. Mater. Chem. A 10, 18822–18833 (2022).Article
Google Scholar
Tsai, M.-D., Chen, Y.-L., Chang, J.-W., Yang, S.-C. & Kung, C.-W. Sulfonate-functionalized two-dimensional metal-organic framework as a “dispersant” for polyaniline to boost its electrochemical capacitive performance. ACS Appl. Energy Mater. 6, 11268–11277 (2023).Article
CAS
Google Scholar
Deria, P. et al. Perfluoroalkane functionalization of NU-1000 via solvent-assisted ligand incorporation: Synthesis and CO2 adsorption. Stud. J. Am. Chem. Soc. 135, 16801–16804 (2013).Article
CAS
Google Scholar
Wang, Z. et al. Fluorinated strategy of node structure of Zr-based MOFMOF for construction of high-performance composite polymer electrolyte membranes. J. Membr. Sci. 645, 120193 (2022).Article
CAS
Google Scholar
Banerjee, M. et al. Postsynthetic modification switches an achiral framework to catalytically active homochiral metal-organic porous materials. J. Am. Chem. Soc. 131, 7524–7525 (2009).Article
CAS
PubMed
Google Scholar
Lalonde, M. et al. Transmetalation: routes to metal exchange within metal–organic frameworks. J. Mater. Chem. A 1, 5453–5468 (2013).Article
CAS
Google Scholar
Das, S., Kim, H. & Kim, K. Metathesis in single crystal: complete and reversible exchange of metal ions constituting the frameworks of metal-organic frameworks. J. Am. Chem. Soc. 131, 3814–3815 (2009).Article
CAS
PubMed
Google Scholar
Zhang, Z. et al. Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO2/CH4 selectivity. Angew. Chem. Int. Ed. 51, 9330–9334 (2012).Article
CAS
Google Scholar
Li, B. et al. Metal-cation-directed de novo assembly of a functionalized guest molecule in the nanospace of a metal-organic framework. J. Am. Chem. Soc. 136, 1202–1205 (2014).Article
CAS
PubMed
Google Scholar
Mao, J. et al. Isolated ni atoms dispersed on Ru nanosheets: high-performance electrocatalysts toward hydrogen oxidation reaction. Nano Lett. 20, 3442–3448 (2020).Article
ADS
CAS
PubMed
Google Scholar
Wang, Z. et al. Titania-supported Cu-single-atom catalyst for electrochemical reduction of acetylene to ethylene at low-concentrations with suppressed hydrogen evolution. Adv. Mater. 35, 2303818 (2023).Article
CAS
Google Scholar
Wang, Q. et al. Photoinduced metastable asymmetric Cu single atoms for photoreduction of CO2 to ethylene. Adv. Energy Mater. 13, 2302692 (2023).Article
CAS
Google Scholar
Lin, J. et al. Macroporous carbon-nitride-supported transition-metal single-atom catalysts for photocatalytic hydrogen production from ammonia splitting. ACS Catal. 13, 11711–11722 (2023).Article
CAS
Google Scholar
Liu, H. et al. Pd–Mn/NC dual single-atomic sites with hollow mesopores for the highly efficient semihydrogenation of phenylacetylene. J. Am. Chem. Soc. 146, 2132–2140 (2024).Article
CAS
PubMed
Google Scholar
Jiang, R. et al. Edge-site engineering of atomically dispersed Fe–N by selective C–N bond cleavage for enhanced oxygen reduction reaction activities. J. Am. Chem. Soc. 140, 11594–11598 (2018).Article
CAS
PubMed
Google Scholar
Sui, J. et al. A general strategy to immobilize single-atom catalysts in metal-organic frameworks for enhanced photocatalysis. Adv. Mater. 34, e2109203 (2022).Article
PubMed
Google Scholar
Wang, J. et al. Precise regulation of the coordination environment of single Co(II) sites in a metal-organic framework for boosting CO2 photoreduction. ACS Catal. 13, 8760–8769 (2023).Article
CAS
Google Scholar
Bai, S. et al. High-efficiency direct methane conversion to oxygenates on a cerium dioxide nanowires supported rhodium single-atom catalyst. Nat. Commun. 11, 954 (2020).Article
ADS
CAS
PubMed
PubMed Central
Google Scholar
Wei, H. et al. Feox-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes. Nat. Commun. 5, 5634 (2014).Article
ADS
CAS
PubMed
Google Scholar
Peralta, R. A. et al. Highly active gas phase organometallic catalysis supported within metal-organic framework pores. J. Am. Chem. Soc. 142, 13533–13543 (2020).Article
CAS
PubMed
Google Scholar
Manna, K. et al. Chemoselective single-site earth-abundant metal catalysts at metal-organic framework nodes. Nat. Commun. 7, 12610 (2016).Article
ADS
CAS
PubMed
PubMed Central
Google Scholar
Otake, K.-i. et al. Enhanced activity of heterogeneous Pd(II) catalysts on acid-functionalized metal-organic frameworks. ACS Catal. 9, 5383–5390 (2019).Article
CAS
Google Scholar
Parshamoni, S., Nasani, R., Paul, A. & Konar, S. Synthesis of a palladium based MOF via an effective post-synthetic modification approach and its catalytic activity towards Heck type coupling reactions. Inorg. Chem. Front. 8, 693–699 (2021).Article
CAS
Google Scholar
He, T. et al. A practice of reticular chemistry: construction of a robust mesoporous palladium metal-organic framework via metal metathesis. J. Am. Chem. Soc. 143, 9901–9911 (2021).Article
CAS
PubMed
Google Scholar
Vahabi, A. H., Norouzi, F., Sheibani, E. & Rahimi-Nasrabadi, M. Functionalized Zr-UiO-67 metal-organic frameworks: structural landscape and application. Coord. Chem. Rev. 445, 214050 (2021).Article
CAS
Google Scholar
Chen, L., Rangan, S., Li, J., Jiang, H. & Li, Y. A molecular Pd(II) complex incorporated into a MOF as a highly active single-site heterogeneous catalyst for C–Cl bond activation. Green. Chem. 16, 3978–3985 (2014).Article
CAS
Google Scholar
Madrahimov, S. T. et al. Gas-phase dimerization of ethylene under mild conditions catalyzed by MOF materials containing (bpy)NiII complexes. ACS Catal. 5, 6713–6718 (2015).Article
CAS
Google Scholar
Young, R. J. et al. Isolating reactive metal-based species in metal-organic frameworks—viable strategies and opportunities. Chem. Sci. 11, 4031–4050 (2020).Article
CAS
PubMed
PubMed Central
Google Scholar
Sawano, T. et al. Metal-organic frameworks stabilize mono(phosphine)–metal complexes for broad-scope catalytic reactions. J. Am. Chem. Soc. 138, 9783–9786 (2016).Article
CAS
PubMed
Google Scholar
Dunning, S. G. et al. A metal-organic framework with cooperative phosphines that permit post‐synthetic installation of open metal sites. Angew. Chem. Int. Ed. 57, 9295–9299 (2018).Article
CAS
Google Scholar
Sikma, R. E. et al. Organoarsine metal-organic framework with cis-diarsine pockets for the installation of uniquely confined metal complexes. J. Am. Chem. Soc. 140, 9806–9809 (2018).Article
CAS
PubMed
Google Scholar
Cargill Thompson, Alexander M. W., Batten, Stuart R., Jeffery, John C., Rees, Leigh H. & Ward, M. D. Some coordination chemistry of the bidentate nitrogen-donor ligand 2-(2-aminophenyl)pyridine. Aust. J. Chem. 50, 109–114 (1997).Article
Google Scholar
Durainatarajan, P., Prabakaran, M., Ramesh, S. & Periasamy, V. Self-assembly on copper surface by using imidazole derivative for corrosion protection. J. Adhes. Sci. Technol. 32, 1733–1749 (2018).Article
CAS
Google Scholar
Lee, J. E. et al. Role of CO-vapors in vapor deposition polymerization. Sci. Rep. 5, 8420 (2015).Article
PubMed
PubMed Central
Google Scholar
Cao, S.-W. et al. Solar-to-fuels conversion over In2O3/g-C3N4 hybrid photocatalysts. Appl. Catal. B: Environ. 147, 940–946 (2014).Article
CAS
Google Scholar
Jiang, G. et al. Surface ligand environment boosts the electrocatalytic hydrodechlorination reaction on palladium nanoparticles. ACS Appl. Mater. Interfaces 13, 4072–4083 (2021).Article
CAS
PubMed
Google Scholar
Pisarevskaya, E. Y., Zolotarevskiy, V. I., Kazanskiy, L. P., Ovsyannikova, E. V. & Alpatova, N. M. Double-stage poly-o-phenylenediamine modification with palladium nanoparticles. Synth. Met. 159, 304–310 (2009).Article
CAS
Google Scholar
Mirkelamoglu, B. & Karakas, G. The role of alkali-metal promotion on CO oxidation over PdO/SnO2 catalysts. Appl. Catal. A: Gen. 299, 84–94 (2006).Article
CAS
Google Scholar
Militello, M. C. & Simko, S. J. Elemental palladium by XPS. Surf. Sci. Spectra 3, 387–394 (1994).Article
ADS
CAS
Google Scholar
Martín, A. J., Mitchell, S., Mondelli, C., Jaydev, S. & Pérez-Ramírez, J. Unifying views on catalyst deactivation. Nat. Catal. 5, 854–866 (2022).Article
Google Scholar
Gole, B., Sanyal, U., Banerjee, R. & Mukherjee, P. S. High loading of Pd nanoparticles by interior functionalization of MOFs for heterogeneous catalysis. Inorg. Chem. 55, 2345–2354 (2016).Article
CAS
PubMed
Google Scholar
Azad, M., Rostamizadeh, S., Estiri, H. & Nouri, F. Ultra-small and highly dispersed Pd nanoparticles inside the pores of ZIF-8: sustainable approach to waste-minimized Mizoroki–Heck cross-coupling reaction based on reusable heterogeneous catalyst. Appl. Organomet. Chem. 33, e4952 (2019).Article
Google Scholar
Wei, Y.-L. et al. Pd(II)-nhdc-functionalized UiO-67 type MOF for catalyzing Heck cross-coupling and intermolecular benzyne–benzyne–alkene insertion reactions. Inorg. Chem. 57, 4379–4386 (2018).Article
CAS
PubMed
Google Scholar
Nuri, A. et al. Pd supported MOFIRMOF-3: heterogeneous, efficient and reusable catalyst for Heck reaction. Catal. Lett. 149, 1941–1951 (2019).Article
CAS
Google Scholar
Dong, D. et al. Postsynthetic modification of single Pd sites into uncoordinated polypyridine groups of a MOF as the highly efficient catalyst for Heck and Suzuki reactions. N. J. Chem. 42, 9317–9323 (2018).Article
CAS
Google Scholar
Nuri, A. et al. Synthesis and characterization of palladium supported amino functionalized magnetic-MOFMOF-MIL-101 as an efficient and recoverable catalyst for Mizoroki–Heck cross-coupling. Catal. Lett. 150, 2617–2629 (2020).Article
CAS
Google Scholar
Furukawa, H. et al. Water adsorption in porous metal-organic frameworks and related materials. J. Am. Chem. Soc. 136, 4369–4381 (2014).Article
CAS
PubMed
Google Scholar
Reinsch, H., Waitschat, S., Chavan, S. M., Lillerud, K. P. & Stock, N. A facile “green” route for scalable batch production and continuous synthesis of zirconium MOFs. Eur. J. Inorg. Chem. 2016, 4490–4498 (2016).Article
CAS
Google Scholar